1. 毕业设计(论文)的内容和要求
完成稳定MOF材料合成和性能探索的工作。
熟悉配位化学的基本原理,掌握相关实验的基本过程。
2. 参考文献
1. Li, L. C.; Matsuda, R.; Tanaka, I.; Sato, H.; Kanoo, P.; Jeon, H. J.; Foo, M. L.; Wakamiya, A.; Murata, Y.; Kitagawa, S. A Crystalline Porous Coordination Polymer Decorated with Nitroxyl Radicals Catalyzes Aerobic Oxidation of Alcohols. J. Am. Chem. Soc. 2014, 136 (21), 7543-7546.2. Dong, Q.; Guo, Y.; Cao, H.; Wang, S.; Matsuda, R.; Duan, J. Accelerated C2H2/CO2 Separation by a Se-Functionalized Porous Coordination Polymer with Low Binding Energy. ACS Appl. Mater. Interfaces 2020, 12 (3), 3764-3772.3. Cui, X. L.; Chen, K. J.; Xing, H. B.; Yang, Q. W.; Krishna, R.; Bao, Z. B.; Wu, H.; Zhou, W.; Dong, X. L.; Han, Y.; Li, B.; Ren, Q. L.; Zaworotko, M. J.; Chen, B. L. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene. Science 2016, 353 (6295), 141-144.4. Wang, K.; Lv, X. L.; Feng, D.; Li, J.; Chen, S.; Sun, J.; Song, L.; Xie, Y.; Li, J. R.; Zhou, H. C. Pyrazolate-Based Porphyrinic Metal-Organic Framework with Extraordinary Base-Resistance. J. Am. Chem. Soc. 2016, 138 (3), 914-919.5. Yang, S. H.; Ramirez-Cuesta, A. J.; Newby, R.; Garcia-Sakai, V.; Manuel, P.; Callear, S. K.; Campbell, S. I.; Tang, C. C.; Schroder, M. Supramolecular binding and separation of hydrocarbons within a functionalized porous metal-organic framework. Nat. Chem. 2015, 7 (2), 121-129.6. Duan, J. G.; Jin, W. Q.; Kitagawa, S. Water-resistant porous coordination polymers for gas separation. Coord. Chem. Rev. 2017, 332, 48-74.7. Duan, J. G.; Higuchi, M.; Horike, S.; Foo, M. L.; Rao, K. P.; Inubushi, Y.; Fukushima, T.; Kitagawa, S. High CO2/CH4 and C-2 Hydrocarbons/CH4 Selectivity in a Chemically Robust Porous Coordination Polymer. Adv. Funct. Mater. 2013, 23 (28), 3525-3530.
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