1. 毕业设计(论文)的内容和要求
研究内容:(1)通过热腐蚀法制备g-C3N4纳米片;(2)制备离子液体/ g-C3N4复合膜;(3)探究膜制备条件对膜的气体分离性能的影响。
具体要求:(1)大量阅读文献(英文文献20篇以上,中文文献10篇以上); (2)熟悉实验室基本仪器的操作; (3)掌握测试表征的基本原理、操作方法; (4)学会膜性能的测试方法; (5)具备独立撰写论文、制作学术PPT并汇报课题的能力。
2. 参考文献
[1] P. Bernardo, E. Drioli, G. Golemme, Membrane Gas Separation: A Review/State of the Art, Industrial Engineering Chemistry Research, 48 (2009) 4638-4663.[2] K. Cao, Z. Jiang, X. Zhang, Y. Zhang, J. Zhao, R. Xing, S. Yang, C. Gao, F. Pan, Highly water-selective hybrid membrane by incorporating g-C3N4 nanosheets into polymer matrix, Journal Of Membrane Science, 490 (2015) 72-83.[3] L. Cheng, G. Liu, W. Jin, Recent Progress in Two-dimensional-material Membranes for Gas Separation, Acta Physico-Chimica Sinica, 35 (2019) 1090-1098.[4] B. Dubertret, T. Heine, M. Terrones, The Rise of Two-Dimensional Materials, Accounts Of Chemical Research, 48 (2015) 1-2.[5] G. Liu, V. Chernikova, Y. Liu, K. Zhang, Y. Belmabkhout, O. Shekhah, C. Zhang, S. Yi, M. Eddaoudi, W.J. Koros, Mixed matrix formulations with MOF molecular sieving for key energy-intensive separations, Nature Materials, 17 (2018) 283.[6] G. Liu, W. Jin, N. Xu, Two-Dimensional-Material Membranes: A New Family of High-Performance Separation Membranes, Angewandte Chemie-International Edition, 55 (2016) 13384-13397.[7] H.B. Park, J. Kamcev, L.M. Robeson, M. Elimelech, B.D. Freeman, Maximizing the right stuff: The trade-off between membrane permeability and selectivity, Science, 356 (2017).[8] J. Ran, T. Pan, Y. Wu, C. Chu, P. Cui, P. Zhang, X. Ai, C.-F. Fu, Z. Yang, T. Xu, Endowing g-C3 N4 Membranes with Superior Permeability and Stability by Using Acid Spacers, Angewandte Chemie (International ed. in English), 58 (2019) 16463-16468.[9] Z. Tian, S. Wang, Y. Wang, X. Ma, K. Cao, D. Peng, X. Wu, H. Wu, Z. Jiang, Enhanced gas separation performance of mixed matrix membranes from graphitic carbon nitride nanosheets and polymers of intrinsic microporosity, Journal Of Membrane Science, 514 (2016) 15-24.[10] S. Wang, X. Li, H. Wu, Z. Tian, Q. Xin, G. He, D. Peng, S. Chen, Y. Yin, Z. Jiang, M.D. Guiver, Advances in high permeability polymer-based membrane materials for CO2 separations, Energy Environmental Science, 9 (2016) 1863-1890.[11] X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J.M. Carlsson, K. Domen, M. Antonietti, A metal-free polymeric photocatalyst for hydrogen production from water under visible light, Nature Materials, 8 (2009) 76-80.[12] Y. Wang, L. Li, Y. Wei, J. Xue, H. Chen, L. Ding, J. Caro, H. Wang, Water Transport with Ultralow Friction through Partially Exfoliated g-C3N4 Nanosheet Membranes with Self-Supporting Spacers, Angewandte Chemie-International Edition, 56 (2017) 8974-8980.[13] Y. Wang, X. Wang, M. Antonietti, Polymeric Graphitic Carbon Nitride as a Heterogeneous Organocatalyst: From Photochemistry to Multipurpose Catalysis to Sustainable Chemistry, Angewandte Chemie-International Edition, 51 (2012) 68-89.[14] M. Xu, T. Liang, M. Shi, H. Chen, Graphene-Like Two-Dimensional Materials, Chemical Reviews, 113 (2013) 3766-3798.[15] F. Zhou, H.N. Tien, W.L. Xu, J.-T. Chen, Q. Liu, E. Hicks, M. Fathizadeh, S. Li, M. Yu, Ultrathin graphene oxide-based hollow fiber membranes with brush-like CO2-philic agent for highly efficient CO2 capture, Nature Communications, 8 (2017).
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