全文总字数:2589字
1. 毕业设计(论文)的内容和要求
光活性的锆基金属-有机框架材料(Zr-MOFs)由于具有较好的稳定性和结构的多样性在可 见光驱动的光催化CO2还原方面具有较好的应用。
然而,现在的体系主要集中于卟啉或者氨基的Zr-MOFs。
此外,Zr-MOFs普遍存在的问题是CO2的吸附能力较弱,这限制了性能的提高。
2. 实验内容和要求
(1)先通过阅读相关文献来达到对课题的初步了解。
(2)设计MOFs的合成路径,并考察其可行性,确定实验条件及评价方法。
实验需要相关原料以及实验和表征设备。
3. 参考文献
1. Shanyong Chen et al. Indolo[3,2-b]carbazole derivative as a fluorescent probe for fluoride ion and carbon dioxide detections[J]. Sensors Organic Framework: Immobilized Molecular Switches in Solid State[J]. Chemistry of Materials, 2015:150828112807001.5. Jiang Hai-Long et al. Pore surface engineering with controlled loadings of functional groups via click chemistry in highly stable metal-organic frameworks.[J]. Journal of the American Chemical Society, 2012, 134(36) : 14690-3.6. Cavka Jasmina Hafizovic et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.[J]. Journal of the American Chemical Society, 2008, 130(42) : 13850-1.7. Imteaz Ahmed,Zubair Hasan,Nazmul Abedin Khan,Sung Hwa Jhung. Adsorptive denitrogenation of model fuels with porous metal-organic frameworks (MOFs): Effect of acidity and basicity of MOFs[J]. Applied Catalysis B: Environmental,2013,129.8. Haibing, Meng, Chong, et al. Optically Controlled Molecular Metallofullerene Magnetism via an Azobenzene-Functionalized Metal-Organic Framework.[J]. Acs Applied Materials Interfaces, 2018.9. Yu X , Wang Z , Buchholz M , et al. Cis-to-trans isomerization of azobenzene investigated by using thin films of metal-organic frameworks[J]. Physical Chemistry Chemical Physics, 2015, 17(35).10. Yu-Hong, Cong-Xue, Liu, et al. TiO2@UiO-68-CIL: A Metal-Organic-Framework-Based Bifunctional Composite Catalyst for a One-Pot Sequential Asymmetric Morita-Baylis-Hillman Reaction.[J]. Inorganic chemistry, 2018.
4. 毕业设计(论文)计划
2021.03.01-03.13 完成翻译和开题报告 2018.03.14-03.17 准备实验材料,熟悉实验技能 2018.03.18-04.30 完成MOFs的制备 2018.05.01-05.20 进行表征与改进 完成中期检查2018.05.21-06.06 完成毕业论文和答辩ppt
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