固体氧化物燃料电池空气电极BaCo0.4Fe0.4Zr0.1Y0.1O3-δ的制备及优化任务书

 2021-10-22 09:10

1. 毕业设计(论文)的内容和要求

1、内容:固体氧化物燃料电池(SOFC)因其高效率、无污染、全固态结构和对多种燃料气体的广泛适应性等,有着广阔的市场前景。

而质子导体基固体氧化物燃料电池以其相对温和的工作温度、较低的成本和可观的应用前景成为一类重要的中低温固体氧化物燃料电池(IT-SOFCs)。

目前,许多研究将传统的阴极材料作为质子导体基SOFC的空气电极,其稳定性与性能并不理想。

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2. 参考文献

[1] 衣宝廉. 燃料电池 [M]. 北京:化学工业出版社, 2000.[2] 陈建新,曾凡蓉,王绍荣等. 固体氧化物燃料电池关键材料及电池堆技术[J]. 化学进展. 23(2/3):463-469 (2011).[3] Zhan Z, Han D, Wu T, et al. A solid oxide cell yielding high power density below 600℃[J]. Rsc Advances, 2012, 2(10): 4075-4078.[4] DUAN C C, TONG J H, SHANG M, et al. Readily processed protonic ceramic fuel cells with high performance at low temperatures[J]. Science, 2015, 349(6254): 1321-1326.[5] Iwahara H, Esaka T, Uchida H, et al. Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production[J]. Solid State Ionics, 1981, 3: 359-363.[6] Demin A, Tsiakaras P. Thermodynamic analysis of a hydrogen fed solid oxide fuel cell based on a proton conductor[J]. International Journal of Hydrogen Energy, 2001, 26(10): 1103-1108.[7] Sun W, Yan L, Shi Z, et al. Fabrication and performance of a proton-conducting solid oxide fuel cell based on a thin BaZr0.8Y0.2O3δ electrolyte membrane[J]. J Power Sources, 2010, 195(15): 47274730.[8] Lei L, Tao Z, Wang X, et al. Intermediate-temperature solid oxide electrolysis cells with thin proton-conducting electrolyte and robust air electrode[J]. J. Mater. Chem. A, 2017, 5(44): 22945-22951.[9] Bi L, Shafi S P, Traversa E. Y-doped BaZrO3 as a chemically stable electrolyte for proton-conducting solid oxide electrolysis cells (SOECs)[J]. J. Mater. Chem. A, 2015, 3(11):5815-5819.[10] Z. Zhao, L. Liu, X. Zhang, et al. High- and low- temperature behaviors of La0.6Sr0.4Co0.2Fe0.8O3δ cathode operating under CO2/H2O-containing atmosphere[J]. Int. J. Hydrogen Energy, 2013, 38, 1536115370.[11] Tong J, Yang W, Zhu B, et al. Investigation of Ideal Zirconium-Doped Perovskite-Type Ceramic Membrane Materials for Oxygen Separation[J]. Journal of Membrane Science, 2002, 203(1):175-189.[12] Sun Z Q, Fabbri E, Bi L, et al. Electrochemical Properties and Intermediate-Temperature Fuel Cell Performance of Dense Yttrium-Doped Barium Zirconate with Calcium Addition[J]. J Am Ceram Soc, 2012, 95(2): 627-635.[13] Kochetova N , Animitsa I , Medvedev D , et al. Recent activity in the development of proton-conducting oxides for high-temperature applications[J]. RSC Adv. 2016, 6(77):73222-73268.[14] Fabbri E , Bi L , Tanaka H , et al. Chemically Stable Pr and Y Co-Doped Barium Zirconate Electrolytes with High Proton Conductivity for Intermediate-Temperature Solid Oxide Fuel Cells[J]. Advanced Functional Materials, 2011, 21(1):158-166.[15] Shang M, Tong J, O'Hayre R. A promising cathode for intermediate temperature protonic ceramic fuel cells: BaCo0.4Fe0.4Zr0.2O3δ[J]. RSC Advances, 2013, 3(36):15769.

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