VS4@Ti3C2/C用于镁二次电池正极材料电化学性能研究任务书

 2021-11-04 09:11

1. 毕业设计(论文)的内容和要求

本课题旨在制备一种高性能的镁二次电池正极材料。

通过将VS4和Ti3C2以不同的比例进行复合,制备出VS4在Ti3C2纳米片上生长的特殊形貌。

该形貌有利于提升VS4的电子电导率,并且可以有效抑制Ti3C2的堆叠。

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2. 参考文献

根据毕业要求指点10.3,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的英文文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。

以下是与本课题相关的部分文献列表:(提供适当参考文献,学生自己按需补充)[1]M. Li, J. Lu, Z. Chen, K. Amine, 30 Years of Lithium-Ion Batteries, ADV. MATER., 30(2018).[2]Z.P. Cano, D. Banham, S. Ye, A. Hintennach, J. Lu, M. Fowler, Z. Chen, Batteries and fuel cells for emerging electric vehicle markets, NAT ENERGY, 3(2018) 279-289.[3]Q. Wang, L. Jiang, Y. Yu, J. Sun, Progress of enhancing the safety of lithium ion battery from the electrolyte aspect, NANO ENERGY, 55(2019) 93-114.[4]F. Han, A.S. Westover, J. Yue, X. Fan, F. Wang, M. Chi, D.N. Leonard, N. Dudney, H. Wang, C. Wang, High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes, NAT ENERGY, 4(2019) 187-196.[5]X. Cheng, R. Zhang, C. Zhao, Q. Zhang, Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review, CHEM. REV., 117(2017) 10403-10473.[6]Y. Guo, H. Li, T. Zhai, Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries, ADV. MATER., 29(2017).[7]Y. Xie, Y. Dall Agnese, M. Naguib, Y. Gogotsi, M.W. Barsoum, H.L. Zhuang, P.R.C. Kent, Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries, ACS NANO, 8(2014) 9606-9615.[8]Y. Xie, Y. Dall'Agnese, M. Naguib, Y. Gogotsi, M.W. Barsoum, H.L. Zhuang, P.R.C. Kent, Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries, ACS NANO, 8(2014) 9606-9615.[9]J. Muldoon, C.B. Bucur, T. Gregory, Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond, CHEM. REV., 114(2014) 11683-11720.[10]R.E. Doe, R. Han, J. Hwang, A.J. Gmitter, I. Shterenberg, H.D. Yoo, N. Pour, D. Aurbach, Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries, Chemical communications (Cambridge, England), 50(2014) 243-245.[11]M. Mao, T. Gao, S. Hou, C. Wang, A critical review of cathodes for rechargeable Mg batteries, CHEM. SOC. REV., 47(2018) 884-8841.[12]P. Saha, M.K. Datta, O.I. Velikokhatnyi, A. Manivannan, D. Alman, P.N. Kumta, Rechargeable magnesium battery: Current status and key challenges for the future, PROG. MATER. SCI., 66(2014) 1-86.[13]D. AU Aurbach, Z. Lu, A. Schechter, Y. Gofer, H. Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich, E. Levi, D. AF Aurbach, Z. Lu, A. Schechter, Y. Gofer, H. Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich, E. Levi, Prototype systems for rechargeable magnesium batteries, NATURE, 6805(2000) 724-727.[14]M. Zhang, A.C. MacRae, H. Liu, Y.S. Meng, CommunicationInvestigation of Anatase-TiO2 as an Efficient Electrode Material for Magnesium-Ion Batteries, J. ELECTROCHEM. SOC., 163(2016) A2368-A2370.[15]T. Koketsu, J. Ma, B.J. Morgan, M. Body, C. Legein, W. Dachraoui, M. Giannini, A. Demortire, M. Salanne, F. Dardoize, H. Groult, O.J. Borkiewicz, K.W. Chapman, P. Strasser, D. Dambournet, Reversible magnesium and aluminium ions insertion in cation-deficient anatase TiO2, NAT. MATER., 16(2017) 1142-1148.[16]L.F. Jiao, H.T. Yuan, Y.J. Wang, H.S. Cao, Y.M. Wang, Mg intercalation properties into open-ended vanadium oxide nanotubes, ELECTROCHEM. COMMUN., 7(2005) 431-436.[17]H.D. Yoo, Y. Liang, H. Dong, J. Lin, H. Wang, Y. Liu, L. Ma, T. Wu, Y. Li, Q. Ru, Y. Jing, Q. An, W. Zhou, J. Guo, J. Lu, S.T. Pantelides, X. Qian, Y. Yao, Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries, NAT COMMUN, 8(2017).[18]X. Sun, P. Bonnick, L.F. Nazar, Layered TiS2 Positive Electrode for Mg Batteries, ACS ENERGY LETT, 1(2016) 297-301.[19]Y. Liang, R. Feng, S. Yang, H. Ma, J. Liang, J. Chen, Rechargeable Mg Batteries with Graphene-like MoS2 Cathode and Ultrasmall Mg Nanoparticle Anode, ADV. MATER., 23(2011) 640.[20]Y. Liu, L. Fan, L. Jiao, Graphene intercalated in graphene-like MoS2: A promising cathode for rechargeable Mg batteries, J. POWER SOURCES, 340(2017) 104-110.

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