1. 毕业设计（论文）的内容和要求
本课题采用水热的方法，合成硫化锰与石墨烯的复合物材料，并通过研究水热时间，水热温度，水热前驱体溶液的浓度等因素，结合现代分析技术，如SEM和XRD等方法，来探讨样品的形貌和晶型等特征。
最后，再通过组装成电池来研究其电化学性能，分析复合后样品的性能情况，最后把整个研究内容写成毕业论文。
毕业论文的内容和要求如下：（1）在第一章文献综述部分，通过文献阅读和总结分析，给出如下内容：锂离子电池的基本信息、负极材料的要求、硫化锰的简介和常见的制备技术研究进展、材料的电解制备技术研究进展等，本课题拟开展的研究内容和预期目标。
2. 参考文献
[1] 吴宇平, 万春荣, 姜长印. 锂离子二次电池 [M]. 北京: 化学工业出版社, 2002.[2] H. Wang, M. Matsui, H. Kuwata, H. Sonoki, Y. Matsuda, X. Shang, Y. Takeda, O. Yamamoto, N. Imanishi, A reversible dendrite-free high-areal-capacity lithium metal electrode, Nat Commun, 8 (2017) 15106[3] 何曼君，陈维孝，董西侠. 高分子物理[M]. 上海:复旦大学出版社, 1990[4] Y. Lu, L. Yu, X.W. Lou, Nanostructured Conversion-type Anode Materials for Advanced Lithium-Ion Batteries, Chem, 4 (2018) 972-996.[5] J.B. Goodenough, K.S. Park, The Li-ion rechargeable battery: a perspective, J Am Chem Soc, 135 (2013) 1167-1176.[6] Y.J. Wang, H. Wu, L. Huang, H. Zhao, Z.F. Liu, X.C. Chen, H. Liu, Y. Zhang, Hierarchically Porous N,S-Codoped Carbon-Embedded Dual Phase MnO/MnS Nanoparticles for Efficient Lithium Ion Storage, Inorg Chem, 57 (2018) 7993-8001.[7] J. Ning, D. Zhang, H. Song, X. Chen, J. Zhou, Branched carbon-encapsulated MnS core/shell nanochains prepared via oriented attachment for lithium-ion storage, Journal of Materials Chemistry A, 4 (2016) 12098-12105. [8] Y. Hao, C. Chen, X. Yang, G. Xiao, B. Zou, J. Yang, C. Wang, Studies on intrinsic phase-dependent electrochemical properties of MnS nanocrystals as anodes for lithium-ion batteries, Journal of Power Sources, 338 (2017) 9-16. [9] R.A. Paredes Camacho, A.-M. Wu, X.-Z. Jin, X.-F. Dong, X.-N. Li, H. Huang, Effective carbon constraint of MnS nanoparticles as high-performance anode of lithium-ion batteries, Journal of Power Sources, 437 (2019). [10] L. Zhang, L. Zhou, H.B. Wu, R. Xu, X.W. Lou, Unusual formation of single-crystal manganese sulfide microboxes co-mediated by the cubic crystal structure and shape, Angew Chem Int Ed Engl, 51 (2012) 7267-7270. [11] R. Wang, B. Li, L. Lai, M. Hou, J. Gao, R. Wu, 3D urchin-like architectures assembled by MnS nanorods encapsulated in N-doped carbon tubes for superior lithium storage capability, Chem Eng J, 355 (2019) 752-759. [12] X. Gao, B. Wang, Y. Zhang, H. Liu, H. Liu, H. Wu, S. Dou, Graphene-scroll-sheathed α-MnS coaxial nanocables embedded in N, S Co-doped graphene foam as 3D hierarchically ordered electrodes for enhanced lithium storage, Energy Storage Materials, 16 (2019) 46-55. [13] D.H. Liu, W.H. Li, Y.P. Zheng, Z. Cui, X. Yan, D.S. Liu, J.W. Wang, Y. Zhang, H.Y. Lu, F.Y. Bai, J.Z. Guo, X.L. Wu, In Situ Encapsulating alpha-MnS into N,S-Codoped Nanotube-Like Carbon as Advanced Anode Material: alpha -> beta Phase Transition Promoted Cycling Stability and Superior Li/Na-Storage Performance in Half/Full Cells, Advanced Materials, 30 (2018).
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