LCFO基中温SOFC阴极材料的制备及表征任务书

 2021-10-22 09:10

1. 毕业设计(论文)的内容和要求

固体氧化物燃料电池(Solid Oxide Fuel Cells,SOFC)是一种可以将储存在燃料和氧化剂中的化学能直接转化成电能的转换装置,具有能量转换效率高,噪音低,无污染等优点。

传统SOFC的操作温度普遍在800-1000℃左右,会导致电池部件失效以及热失配等一系列问题,降低工作温度到600-800℃可以解决这一问题,但是会降低阴极侧氧还原反应(ORR)活性,增大极化损失,同样会导致电池效率降低。

因此,开发适用于中温SOFC的阴极材料具有重要意义。

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2. 参考文献

根据毕业要求指点2.3,毕设期间要进行研究现状调查与总结,要求在开题报告及毕业设计(论文)中涉及的参考文献不少于20篇,其中近5年不少于8篇,英文文献不少于5篇。

以下是与本课题相关的部分文献列表:(学生在此基础上,自行查阅补充)[1] 黄端平, 徐庆, 陈文, 等. 新型中温固体氧化物燃料电池阴极材料的研究[J]. 陶瓷学报, 2006(03):275-280.[2] Li H, Sun L, Li Q, et al. Electrochemical performance of double perovskite Pr2NiMnO6 as a potential IT-SOFC cathode[J]. International Journal of Hydrogen Energy, 2015,40(37):12761-12769.[3] Wang L J, Xie P C, Bian L Z, et al. Performance of Ca-doped GdBa1-xCaxFe2O5 delta(x=0, 0.1) as cathode materials for IT-SOFC application[J]. Catalysis Today, 2018,318(SI):132-136.[4] 邵宗平. 中低温固体氧化物燃料电池阴极材料[J]. 化学进展, 2011,23(Z1):418-429.[5] Jiang S P. A comparison of O-2 reduction reactions on porous (La,Sr)MnO3 and (La,Sr)(Co,Fe)O-3 electrodes[J]. Solid State Ionics, 2002,146(1-2):1-22.[6] Mai A, Haanappel V, Uhlenbruck S, et al. Ferrite-based perovskites as cathode materials for anode-supported solid oxide fuel cells Part I. Variation of composition[J]. Solid State Ionics, 2005,176(15-16): 1341-1350.[7] Leng Y, Chan S H, Liu Q. Development of LSCF-GDC composite cathodes for low-temperature solid oxide fuel cells with thin film GDC electrolyte[J]. International Journal of Hydrogen Energy, 2008,33(14):3808-3817.[8] Tai L W, Nasrallah M M, Anderson H U, et al. Structure and Electrical-perperties of La1-xSrxCo1-yFeyO3. 1. The System La0.8Sr0.2Co1-yFeyO3[J]. Solid State Ionics, 1995,76(3-4):259-271.[9] Miller E C, Gao Z, Barnett S A. Fabrication of Solid Oxide Fuel Cells with a Thin (La0.9Sr0.1)(0.98)(Ga0.8Mg0.2)O3-delta Electrolyte on a Sr0.8La0.2TiO3 Support[J]. Fuel Cells, 2013,13(6):1060-1067.[10] Shao Z P, Haile S M. A high-performance cathode for the next generation of solid-oxide fuel cells[J]. Nature, 2004,431(7005):170-173.[11] Mahmud L S, Muchtar A, Somalu M R. Challenges in fabricating planar solid oxide fuel cells: A review[J]. Renewable Sustainable Energy Reviews, 2017,72:105-116.[12] Baharuddin N A, Muchtar A, Somalu M R. Short review on cobalt-free cathodes for solid oxide fuel cells[J]. International Journal of Hydrogen Energy, 2017,42(14SI):9149-9155.[13] Ai N, Lu Z, Chen K F, et al. Low temperature solid oxide fuel cells based on Sm0.2Ce0.8O1.9 films fabricated by slurry spin coating[J]. Journal of Power Sources, 2006,159(1):637-640.[14] Vohs J M, Gorte R J. High-Performance SOFC Cathodes Prepared by Infiltration[J]. Advanced Materials, 2009,21(9):943-956.

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