Cu3(BTC)2成型体的制备及吸附研究任务书

 2021-10-06 12:10

1. 毕业设计(论文)的内容和要求

1、查阅壳聚糖的酸性胶凝过程和Cu3(BTC)2制备的相关文献,了解课题的研究重点,筛选出与本课题相关性高的文献。

同时阅读课题的相关外文文献,进行总结归纳,并设计实验方案,制定实验计划。

2、熟悉实验仪器的正确使用,提高实验技能,合理规划实验进程。

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2. 参考文献

[1] 魏文英, 方健, 孔海宁,韩金玉,常贺英等. 金属有机骨架材料的合成及应用研究[J]. 化学进展. 2005, 17: 1110~1115[2] Schlichte K,Kratzke T; Kaskel S. Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound CU3(BTC)(2)[J]. Microporous and Mesoporous Materials, 2004, 73: 81~88.[3] Alaerts L,Seguin E,Poelman H, et al. Probing the Lewis acidity and catalytic activity of the metal-organic framework Cu-3(btc)(2) (BTC = benzene-1,3,5-tricarboxylate)[J]. Chemistry-a European Journal, 2006, 12: 7353~7363.[4] Hartmann M,Kunz S,Himsl D, et al. Adsorptive separation of isobutene and isobutane on Cu(3)(BTC)(2)[J]. Langmuir, 2008, 24: 8634~8642.[5] Jee B,Eisinger K,Gul-E-Noor F, et al. Continuous Wave and Pulsed Electron Spin Resonance Spectroscopy of Paramagnetic Framework Cupric Ions in the Zn(II) Doped Porous Coordination Polymer Cu3-xZnx(btc)(2)[J]. Journal of Physical Chemistry C, 2010, 114: 16630~16639.[6] Khan N A,Haque E; Jhung S H. Rapid syntheses of a metal-organic framework material Cu-3(BTC)(2)(H2O)(3) under microwave: a quantitative analysis of accelerated syntheses[J]. Physical Chemistry Chemical Physics, 2010, 12: 2625~2631.[7] Gul-E-Noor F,Jee B,Poeppl A, et al. Effects of varying water adsorption on a Cu-3(BTC)(2) metal-organic framework (MOF) as studied by H-1 and C-13 solid-state NMR spectroscopy[J]. Physical Chemistry Chemical Physics, 2011, 13: 7783~7788.[8] Gul-E-Noor F,Jee B,Mendt M, et al. Formation of Mixed Metal Cu3-xZnx(btc)(2) Frameworks with Different Zinc Contents: Incorporation of Zn2 into the Metal-Organic Framework Structure as Studied by Solid-State NMR[J]. Journal of Physical Chemistry C, 2012, 116: 20866~20873.[9] Huang L,Joshi K L,van Duin A C T, et al. ReaxFF molecular dynamics simulation of thermal stability of a Cu-3(BTC)(2) metal-organic framework[J]. Physical Chemistry Chemical Physics, 2012, 14: 11327~11332.[10] Majano G; Perez-Ramirez J. Scalable Room-Temperature Conversion of Copper(II) Hydroxide into HKUST-1 (Cu3(btc)2)[J]. Advanced Materials, 2013, 25: 1052~1057.[11] Zacher D,Liu J,Huber K, et al. Nanocrystals of Cu-3(btc)(2) (HKUST-1): a combined time-resolved light scattering and scanning electron microscopy study[J]. Chemical Communications, 2009, 9: 1031~1033.[12] Wee L H,Bajpe S R,Janssens N, et al. Convenient synthesis of Cu-3(BTC)(2) encapsulated Keggin heteropolyacid nanomaterial for application in catalysis[J]. Chemical Communications, 2010, 46: 8186~8188.[13] Mustafa D,Breynaert E,Bajpe S R, et al. Stability improvement of Cu-3(BTC)(2) metal-organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate[J]. Chemical Communications, 2011, 47: 8037~8039.[14] Ye J-y; Liu C-j. Cu-3(BTC)(2): CO oxidation over MOF based catalysts[J]. Chemical Communications, 2011, 47: 2167~2169.[15] Liu Y D,Kim J,Ahn W-S, et al. Novel electrorheological properties of a metal-organic framework Cu-3(BTC)(2)[J]. Chemical Communications, 2012, 48: 5635~5637.

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