电子载体1-Methoxy PMS以及甲臜染料WST-8的合成与应用任务书

 2021-10-22 09:10

1. 毕业设计(论文)的内容和要求

查阅相关文献及专业书籍了1-甲基pms,和甲臜染料wst-8的现状研究,了解已有成果以及存在的问题,对论文的研究方向有较深入的认识。

合成并提纯1-甲基PMS,WST-8,确定其分子结构。

培养学生独立思考及动手做实验的能力,养成良好的科研习惯。

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2. 参考文献

[1] X. Chen, G. Zhou, X. Peng and J. Yoon, Biosensors and chemosensors based on the optical responses of polydiacetylenes Chem. Soc. Rev., 2012, 41,4610-4630.[2] J. Lee, C. W. Lee and J.-M. Kim, A Magnetically Responsive Polydiacetylene Precursor for Latent Fingerprint Analysis, ACS Appl. Mater. Interfaces, 2016, 8, 6245-6251.[3] S. Lee, J.-Y. Kim, X. Chen and J. Yoon, Recent progress in stimuli-induced polydiacetylenes for sensing temperature, chemical and biological targets, Chem. Commun, 2016, 52, 9178-9196.[4] D.-H. Park, W. Jeong, M. Seo, B. J. Park and J.-M. Kim, Inkjet-Printable Amphiphilic Polydiacetylene Precursor for Hydrochromic Imaging on Paper, Adv. Funct. Mater., 2016, 26, 498-506.[5] M. Seo, D. H. Park, C. W. Lee, J. Jaworski and J. M. Kim, Fluorometric Measurement of Individual Stomata Activity and Transpiration via a "Brush-on", Water-Responsive Polymer, Sci. Rep., 2016, 6, 32394.[6] M. Seo, D.-H. Park, B. J. Park and J.-M. Kim, Flexible patch-type hydrochromic polydiacetylene sensor for human sweat pore mapping, J. Appl. Polym. Sci., 2017, 134, 44419.[7] J. Park, S. K. Ku, D. Seo, K. Hur, H. Jeon, D. Shvartsman, H.-K. Seok, D. J. Mooney and K. Lee, Label-free bacterial detection using polydiacetylene liposomes, Chem. Commun., 2016, 52, 10346-10349.[8] Q. Xu, S. Lee, Y. Cho, M. H. Kim, J. Bouffard and J. Yoon, Polydiacetylene-based colorimetric and fluorescent chemosensor for the detection of carbon dioxide, J. Am. Chem. Soc., 2013, 135, 17751-4.[9] S. Lee, H. Cheng, M. Chi, Q. Xu, X. Chen, C. Y. Eom, T. D. James, S. Park and J. Yoon, Sensing and antibacterial activity of imidazolium-based conjugated polydiacetylenes, Biosens Bioelectron., 2016, 77, 1016-9.[10] W. Baek, J. M. Heo, S. Oh, S. H. Lee, J. Kim, J. F. Joung, S. Park, H. Chung and J. M. Kim, Photoinduced reversible phase transition of azobenzene-containing polydiacetylene crystals, Chem. Commun. 2016, 52, 14059-14062.[11] D. J. Ahn, E. H. Chae, G. S. Lee, H. Y. Shim, T. E. Chang, K. D. Ahn and J. M. Kim, Colorimetric reversibility of polydiacetylene supramolecules having enhanced hydrogen-bonding under thermal and pH stimuli, J. Am. Chem. Soc., 2003, 125, 8976-8977.[12] M. Okaniwa, Y. Oaki and H. Imai, Intercalation-Induced Tunable Stimuli-Responsive Color-Change Properties of Crystalline Organic Layered Compound, Adv. Funct. Mater., 2016, 26, 3463-3471.[13] X. Chen and J. Yoon, A thermally reversible temperature sensor based on polydiacetylene: Synthesis and thermochromic properties, Dyes and Pigments, 2011, 89, 194-198.[14] S. Lee, J. Lee, M. Lee, Y. K. Cho, J. Baek, J. Kim, S. Park, M. H. Kim, R. Chang and J. Yoon, Construction and Molecular Understanding of an Unprecedented, Reversibly Thermochromic Bis-Polydiacetylene, Adv. Funct. Mater., 2014, 24, 3699-3705.[15] J. Lee, H. T. Chang, H. An, S. Ahn, J. Shim and J.-M. Kim, A protective layer approach to solvatochromic sensors, Nat. Commun., 2013, 4, 2461.

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