铁修饰的氧化铝负载铂催化剂的制备及理化性质研究任务书

 2021-10-23 09:10

1. 毕业设计(论文)的内容和要求

1、学习实验室规范实验操作和安全知识;2、查阅文献,了解与本课题相关的研究发展状况; 3、开展铁修饰的氧化铝负载铂催化剂的制备;4、制备铁修饰的氧化铝负载铂催化剂,用XRD、 BET、CO、H2化学吸附等技术研究铁修饰对氧化铝负载铂催化剂的物相、比表面积、铂分散度和氢吸附能力等理化性质的影响规律; 5、会使用origin、jade、TP-5080全自动吸附仪数据分析系统等软件处理实验数据; 6、撰写毕业论文,准备论文答辩。

2. 参考文献

[1] Feng Li, Jinrong Liang, Keliang Wang, et al. Fe-Promoted Pt-Fe/Al2O3 Catalyst Prepared by Microemulsion Technique for m-Chloronitrobenzene Hydrogenation[J]. Russian Journal of Physical Chemistry A, 2018,92(7):1279-1284.[2] Haisheng Wei, Yujing Ren, Aiqin Wang, et al. FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselectivehydrogenation of functionalized nitroarenes[J].Nature Communications, 2014,5:5634. [3] Haisheng Wei,Yujing Ren, Aiqin Wang, et al.Remarkable effffect of alkalis on the chemoselective hydrogenation of functionalized nitroarenes over high-loading Pt/FeOx catalysts[J]. Chemical Science,2017,8:5126-5131.[4] Wengang Liu, Leilei Zhang, Wensheng Yan,et al. Single-atom dispersed CoNC catalyst: structure identification and performance for hydrogenative coupling of nitroarenes[J]. Chemical Science,2016, 7:5758-5764.[5] Yujing Ren, Haisheng Wei, Oxygen surface groups of activated carbon steer the chemoselective hydrogenation of substituted nitroarenes over nickel nanoparticles[J]. Chemical Communication, 2017, 53:1969-1972.[6] Gang Xu, Haisheng Wei,Yujing Ren, et al. Chemoselective hydrogenation of 3-nitrostyrene over a Pt/FeOx pseudo-single-atom-catalyst in CO2-expanded liquids[J].Green Chemistry, 2016, 18:1332-1338.[7] Yuan Tan, Xiao Yan Liu, Leilei Zhang, et al. ZnAl-Hydrotalcite-Supported Au25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene [J].Angewandte Chemie International Edition, 2017, 56:2709-2713 .[8] Yuan Tan, Xiao Yan Liu, Lin Li, et al. Effects of divalent metal ions of hydrotalcites on catalytic behavior of supported gold nanocatalysts for chemoselective hydrogenation of 3-nitrostyrene[J]. Journal of Catalysis, 2018, 364:174-182.[9] 汪丽,何代平,廖运文,等. 过渡金属改性的 Pt/n-Al2O3在肉桂醛加氢反应中的催化性能[J]. 应用化工, 2011,40(9):1532-1535.[10] 袁信,周键,田森林,等. 过渡金属负载 γ-Al2O3对HCN催化水解性能的影响[J]. 环境科学研究,2014,27(12):1465-1471.[11] 石秀娟,梁文俊,李 坚, 等. 过渡金属Ni对Pd / Al2O3催化剂甲烷催化燃烧性能的影响[J]. 工业催化, 2017,25(5):33-38.

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