咪唑硼鎓阳离子类自燃型离子液体的制备和模拟研究任务书

 2021-10-23 09:10

1. 毕业设计(论文)的内容和要求

1. 查阅、整理文献资料,加深对自己课题的理解,并撰写开题报告。

2. 要求学生对分离工程、有机与分析化学、仪器分析等学科复习,从而对以后自燃型离子液体性能测试实验、谱图分析打下基础。

3. 主要研究通过使用咪唑衍生物以及硼烷络合反应生成自燃型离子液体,通过红外核磁等表征手段进行表征。

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2. 参考文献

[1] Schneider S, Hawkins T, Rosander M, et al. Ionic liquids as hypergolic fuels[J]. Energy A European Journal, 2010, 16(10): 3114-3120.[5] Zhang Q, Yin P, Zhang J, et al. Cyanoborohydride‐Based Ionic Liquids as Green Aerospace Bipropellant Fuels[J]. ChemistryA European Journal, 2014, 20(23): 6909-6914.[6] Wang K, Zhang Y, Chand D, et al. Boronium‐Cation‐Based Ionic Liquids as Hypergolic Fluids[J]. ChemistryA European Journal, 2012, 18(52): 16931-16937.[7] Chand D, Zhang J, Shreeve J M. Borohydride Ionic Liquids as Hypergolic Fuels: A Quest for Improved Stability[J]. ChemistryA European Journal, 2015, 21(38): 13297-13301.[8] Huang S, Qi X, Zhang W, et al. Exploring Sustainable Rocket Fuels:[Imidazolyl Amine BH2] ‐Cation‐Based Ionic Liquids as Replacements for Toxic Hydrazine Derivatives[J]. ChemistryAn Asian Journal, 2015, 10(12): 2725-2732.[9] Liu T, Qi X, Huang S, et al. Exploiting hydrophobic borohydride-rich ionic liquids as faster-igniting rocket fuels[J]. Chemical Communications, 2016, 52(10): 2031-2034.[10] Zhang W, Qi X, Huang S, et al. Super-base-derived hypergolic ionic fuels with remarkably improved thermal stability[J]. Journal of Materials Chemistry A, 2015, 3(41): 20664-20672.[11] Zhang W, Qi X, Huang S, et al. Bis (borano) hypophosphite-based ionic liquids as ultrafast-igniting hypergolic fuels[J]. Journal of Materials Chemistry A, 2016, 4(23): 8978-8982.[12] Huang S, Qi X, Liu T, et al. Towards Safer Rocket Fuels: Hypergolic Imidazolylidene‐Borane Compounds as Replacements for Hydrazine Derivatives[J]. ChemistryA European Journal, 2016, 22(29): 10187-10193.[13] Fareghi-Alamdari R, Ghorbani-Zamani F, Zekri N. Synthesis and hypergolic activity evaluation of some new ammonium-imidazolium based ionic liquids[J]. RSC Advances, 2016, 6(31): 26386-26391.[14] Li X, Wang C, Li H, et al. Bishydrobis (tetrazol-1-yl) borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels[J]. Journal of Materials Chemistry A, 2017, 5(30): 15525-15528.[15] Li X, Huo H, Li H, et al. Cyanotetrazolylborohydride (CTB) anion-based ionic liquids with low viscosity and high energy capacity as ultrafast-igniting hypergolic fuels[J]. Chemical Communications, 2017, 53(59): 8300-8303.[16] Liu T, Qi J, Wang B, et al. Rational Design and Facile Synthesis of Boranophosphate Ionic Liquids as Hypergolic Rocket Fuels[J]. ChemistryA European Journal, 2018.[17] Huang S, Zhang W, Liu T, et al. Towards N‐Alkylimidazole Borane‐based Hypergolic Fuels[J]. ChemistryAn Asian Journal, 2016, 11(24): 3528-3533.[18] Li X, Lu T, Nan J, et al. Hydrophobic Hydrolytic‐Stable N‐Alkylimidazole‐Cyanoborane Complexes as Ultrafast‐Igniting Hypergolic Fuels[J]. ChemistrySelect, 2018, 3(9): 2548-2552.

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