介孔氧化亚钴的制备及其对苯乙烯环氧化催化性能的研究任务书

 2021-10-24 03:10

1. 毕业设计(论文)的内容和要求

内容:制备介孔氧化亚钴催化剂,并探究其在苯乙烯环氧化的催化性能。

基本要求:1.查阅相关文献,具备英文文献阅读、整理和归纳的能力;2.掌握催化剂合成过程,及其一系列表征。

2. 参考文献

1. C. Weerakkody et al., Controllable synthesis of mesoporous cobalt oxide for peroxide free catalytic epoxidation of alkenes under aerobic conditions. Appl Catal B-Environ 221, 681-690 (2018).2. M. Pang et al., Ethanol-assisted solvothermal synthesis of porous nanostructured cobalt oxides (CoO/Co3O4) for high-performance supercapacitors. Chem Eng J 280, 377-384 (2015).3. D. Gu et al., Highly Ordered Mesoporous Cobalt-Containing Oxides: Structure, Catalytic Properties, and Active Sites in Oxidation of Carbon Monoxide. J. Am. Chem. Soc. 137, 11407-11418 (2015).4. J. S. Do, W. H. Jo, R. F. Dai, Characterization of cobalt monoxide thin film modified with silicon dioxide prepared by the cathodic deposition for lithium-ion battery. Journal of the Taiwan Institute of Chemical Engineers 51, 88-95 (2015).5. J. Rosen, G. S. Hutchings, F. Jiao, Ordered mesoporous cobalt oxide as highly efficient oxygen evolution catalyst. J. Am. Chem. Soc. 135, 4516-4521 (2013).6. J. Sebastian, K. M. Jinka, R. V. Jasra, Effect of alkali and alkaline earth metal ions on the catalytic epoxidation of styrene with molecular oxygen using cobalt(II)-exchanged zeolite X. Journal of Catalysis 244, 208-218 (2006).7. Y. Y. Yan, T. J. Wang, J. P. Guo, M. Y. Huang, Y. Y. Jiang, Aerobic epoxidation of styrene catalyzed by magnesium oxide supported polytitazane cobalt(III) complexes. Chinese Chemical Letters 7, 749-752 (1996).8. H. L. Su, Z. F. Li, Q. S. Huo, J. Q. Guan, Q. B. Kan, Immobilization of transition metal (Fe2 , Co2 , VO2 or Cu2 ) Schiff base complexes onto graphene oxide as efficient and recyclable catalysts for epoxidation of styrene. Rsc Advances 4, 9990-9996 (2014).9. Y. Li et al., Highly efficient CoOx/SBA-15 catalysts prepared by atomic layer deposition for the epoxidation reaction of styrene. Catalysis Science Technology 7, 2032-2038 (2017).10. Q. H. Tang, Q. H. Zhang, H. L. Wu, Y. Wang, Epoxidation of styrene with molecular oxygen catalyzed by cobalt(II)-containing molecular sieves. Journal of Catalysis 230, 384-397 (2005).11. A. Askarinejad, M. Bagherzadeh, A. Morsali, Catalytic performance of Mn3O4 and Co3O4 nanocrystals prepared by sonochemical method in epoxidation of styrene and cyclooctene. Appl. Surf. Sci. 256, 6678-6682 (2010).

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