离子液体/金属有机骨架复合材料的制备以及二氧化碳的环加成反应中性能探索任务书

 2021-10-24 03:10

1. 毕业设计(论文)的内容和要求

1. 查阅、整理文献资料,加深对自己课题的理解,并撰写开题报告。

2. 要求学生对四大化学等学科复习,从而对以后催化剂性能测试实验、谱图分析打下基础。

3. 主要研究金属有机框架与离子液体的复合材料制备一种高效催化剂用于CO2的环加成反应,并用XRD、FT-IR、SEM电镜等表征手段进行表征。

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2. 参考文献

[1] Song Q W, Zhou Z H, He L N. Efficient, selective and sustainable catalysis of carbon dioxide [J]. Green Chem., 2017, 19(16): 37073728.[2] 徐如人, 庞文琴, 于吉红等. 分子筛与多孔材料化学 [M],北京,科学出版社,2004[3] 邓友全. 离子液体性质、制备与应用 [M]. 北京, 中国石化出版社, 2006[4] Wang J, Huang L, Yang R, et al. Recent advances in solid sorbents for CO2 capture and new development trends [J]. Energy Environ. Sci., 2014, 7(11): 34783518.[5] Mondal M K, Balsora H K, Varshney P. Progress and trends in CO2 capture/separation technologies: a review [J]. Energy, 2012, 46(1): 431441.[6] Khatri R A, Chuang S S C, Soong Y, et al. Thermal and chemical stability of regenerable solid amine sorbent for CO2 capture [J]. Energy Fuels, 2006, 20(4): 15141520.[7] Wang Q, Luo J, Zhong Z, et al. CO2 capture by solid adsorbents and their applications: current status and new trends [J]. Energy Environ. Sci., 2011, 4(1): 4255.[8] Zhu Y, Murali S, Stoller M D, et al. Carbon-based supercapacitors produced by activation of graphene [J]. Science, 2011, 332(6037): 15371541.[9] Zhang Z, Zhao Y, Gong Q, et al. MOFs for CO2 capture and separation from flue gas mixtures: the effect of multifunctional sites on their adsorption capacity and selectivity [J]. Chem. Commun., 2013, 49(7): 653661.[10] Liu Y, Wang Z U, Zhou H C. Recent advances in carbon dioxide capture with metal‐organic frameworks [J]. Greenh. Gases, 2012, 2(4): 239259.[11] Luo Y, Li B, Wang W, et al. Hypercrosslinked aromatic heterocyclic microporous polymers: a new class of highly selective CO2 capturing materials [J]. Adv. Mater., 2012, 24(42): 57035707.

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