有序介孔碳包裹的聚离子液体催化剂的制备及在CO2的转化中的性能测试任务书

 2021-10-24 03:10

1. 毕业设计(论文)的内容和要求

1. 查阅、整理文献资料,加深对自己课题的理解,并撰写开题报告。

2. 要求学生对分离工程、无机与分析化学、仪器分析等学科复习,从而对以后催化性能测试实验、谱图分析打下基础。

3. 主要研究通过季氨化制备离子液体,以及通过溶剂挥发自组装制备有序介孔碳材料,然后通过浸渍制备有序介孔碳材料包裹的聚离子液体,并用氢核磁共振、XRD、元素分析等表征手段进行表征。

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2. 参考文献

[1] Liu Q, Wu L, Jackstell R, et al. Using carbon dioxide as a building block inorganic synthesis[J]. Nat. Commun, 2015, 6: 5933.[2] Maeda C, Taniguchi T, Ogawa K, et al. Bifunctional Catalysts Based on m‐Phenylene‐Bridged Porphyrin Dimer and Trimer Platforms: Synthesis of CyclicCarbonates from Carbon Dioxide and Epoxides[J]. Angew. Chem. Int. Ed., 2015,54(1): 134-138.[3] Decortes A, Castilla A M, Kleij A W. Salen‐Complex‐Mediated Formation ofCyclic Carbonates by Cycloaddition of CO2 to Epoxides[J]. Angew. Chem. Int.Ed., 2010, 49(51): 9822-9837.[4] Clements J H. Reactive applications of cyclic alkylene carbonates[J]. Ind. Eng.Chem. Res., 2003, 42(4): 663-674.[5] North M, Pasquale R. Mechanism of cyclic carbonate synthesis from epoxidesand CO2[J]. Angew. Chem. Int. Ed., 2009, 121(16): 2990-2992.[6] Bhanage B M, Fujita S, Ikushima Y, et al. Synthesis of dimethyl carbonate andglycols from carbon dioxide, epoxides and methanol using heterogeneous Mgcontaining smectite catalysts: effect of reaction variables on activity andselectivity performance[J]. Green Chem., 2003, 5(1): 71-75.[7] Takahashi T, Watahiki T, Kitazume S, et al. Synergistic hybrid catalyst for cycliccarbonate synthesis: Remarkable acceleration caused by immobilization ofhomogeneous catalyst on silica[J]. Chem. Commun., 2006 (15): 1664-1666.[8] Tsutsumi Y, Yamakawa K, Yoshida M, et al. Bifunctional organocatalyst foractivation of carbon dioxide and epoxide to produce cyclic carbonate: betaine as anew catalytic motif[J]. Org. Lett., 2010, 12(24): 5728-5731.[9] Udayakumar S, Park S W, Park D W, et al. Immobilization of ionic liquid on博士学位论文187hybrid MCM-41 system for the chemical fixation of carbon dioxide on cycliccarbonate[J]. Catal. Commun., 2008, 9(7): 1563-1570.[10]Zhou H, Wang Y M, Zhang W Z, et al. N-Heterocyclic carbene functionalizedMCM-41 as an efficient catalyst for chemical fixation of carbon dioxide[J]. GreenChem., 2011, 13(3): 644-650.[11]Ramidi P, Munshi P, Gartia Y, et al. Synergistic effect of alkali halide and Lewisbase on the catalytic synthesis of cyclic carbonate from CO2 and epoxide[J].Chem. Phys. Lett., 2011, 512(4-6): 273-277.[12]Whiteoak C J, Henseler A H, Ayats C, et al. Conversion of oxiranes and CO2 toorganic cyclic carbonates using a recyclable, bifunctional polystyrene-supportedorganocatalyst[J]. Green Chem., 2014, 16(3): 1552-1559.

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