基于高性能阴极材料(Ba0.5Sr0.5)xCo0.8Fe0.2O3-δ (x=1,1.5,2)在质子导体燃料电池上的运用任务书

 2021-10-25 09:10

1. 毕业设计(论文)的内容和要求

毕业论文内容:固态氧化物燃料电池(SOFC)在过去几十年中因其高效率,低排放并且能从氢,甲烷,乙醇,多种天然化学燃料转直接化为电能而受到了研究界和工业界的广泛关注。

然而,基于传统的钇稳定的氧化锆(YSZ)电解质的SOFC的高工作温度由于高成本和电池组件兼容性的挑战而阻碍了其商业化。

SOFC技术商业化的关键步骤是将工作温度降至400C650C,同时保持足够的功率输出。

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2. 参考文献

[1] 衣宝廉. 燃料电池[M] . 北京:化学工业出版社,2000. [2] 韩敏芳, 彭亦萍. 固体氧化物燃料电池材料及制备[M].北京:科学出版社, 2004.[3] Shao, Z., Haile, S. M., Ahn, J., Ronney, P. D., Zhan, Z., Barnett, S. A. A thermally self-sustained micro solid-oxide fuel-cell stack with high power density. Nature, 2005, 435(7043), 795.[4] Zhu, T., Troiani, H.E., Mogni, L.V., Han, M., and Barnett, S.A. Ni-substituted Sr(Ti,Fe)O3 SOFC anodes: achieving high performance via metal alloy nanoparticle exsolution[J]. Joule, 2018, 478496.[5] Hua, B., Yan, N., Li, M., Sun, Y.F., Zhang, Y.Q., Li, J., Etsell, T., Sarkar, P., and Luo, J.L. Anode-engineered protonic ceramic fuel cell with excellent performance and fuel compatibility[J]. Advanced Materials. 2016, 28, 89228926.[6] Fabbri, E., Bi, L., Pergolesi, D., and Traversa, E. Towards the next generation of solid oxide fuel cells operating below 600 C with chemically stable proton-conducting electrolytes[J]. Advanced Materials. 2012, 24, 195208.[7] Duan, C., Kee, R., Zhu, H., Sullivan, N., Zhu, L., Bian, L., OHayre, R. Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production. Nature Energy, 2019, 4(3), 230-240.[8] Chen, Y., Chen, Y., Ding, D., Ding, Y., Choi, Y., Zhang, L., Lu, Q. A robust and active hybrid catalyst for facile oxygen reduction in solid oxide fuel cells. Energy Environmental Science, 2017, 10(4), 964-971.[9] Li, M., Zhao, M., Li, F., Zhou, W., Peterson, V. K., Xu, X., Zhu, Z. A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 C. Nature communications, 2017, 8, 13990.[10] Chen Y, Choi Y M, Yoo S, et al. A highly efficient multi-phase catalyst dramatically enhances the rate of oxygen reduction[J]. Joule, 2018, 2(5): 938-949.[11] Chen Y, Yoo S, Zhang W, et al. Effective Promotion of Oxygen Reduction Reaction by in situ Formation of nano-structured Catalyst[J]. ACS Catalysis, 2019, 9(8): 7137-7142

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