MOR分子筛膜的制备及渗透汽化脱水分离研究任务书

 2021-10-26 09:10

1. 毕业设计(论文)的内容和要求

内容:研究中空纤维载体上MOR分子筛膜的制备,考察水热合成时间,水硅比的影响,考察载体表面预处理对膜性能的影响。

将制备的膜用于乙醇/水,异丙醇/水等体系的分离,考察MOR分子筛膜在酸性体系下的渗透汽化性能。

要求:1、查阅相关的中英文文献,整理归纳总结相关内容;2、熟悉渗透汽化以及蒸汽渗透的原理;3、具备实验数据分析处理的能力,使用origin作图;4、规范书写毕业论文,符合论文格式与内容要求,准备答辩PPT。

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2. 参考文献

[1] A.I. Serykh, Optical properties of indium-exchanged mordenite zeolite, Microporous And Mesoporous Materials, 275 (2019) 147-151.[2] Y. Li, M. Zhu, N. Hu, F. Zhang, T. Wu, X. Chen, H. Kita, Scale-up of high performance mordenite membranes for dehydration of water-acetic acid mixtures, Journal Of Membrane Science, 564 (2018) 174-183.[3] M.-H. Zhu, X.-M. Hua, Y.-S. Liu, H.L. Hu, Y.-Q. Li, N. Hu, I. Kumakiri, X.-S. Chen, H. Kita, Influences of Synthesis Parameters on Preparation of Acid-Stable and Reproducible Mordenite Membrane, Industrial Engineering Chemistry Research, 55 (2016) 12268-12275.[4] M.-H. Zhu, Z.-J. Feng, X.-M. Hua, H.-l. Hu, S.-L. Xia, N. Hu, Z. Yang, I. Kumakiri, X.S. Chen, H. Kita, Application of a mordenite membrane to the esterification of acetic acid and alcohol using sulfuric acid catalyst, Microporous And Mesoporous Materials, 233 (2016) 171-176.[5] L. Li, J. Yang, J. Li, P. Han, J. Wang, Y. Zhao, J. Wang, J. Lu, D. Yin, Y. Zhang, Synthesis of high performance mordenite membranes from fluoride containing dilute solution under microwave-assisted heating, Journal Of Membrane Science, 512 (2016) 83-92.[6] Y. Zhang, Y. Nakasaka, T. Tago, A. Hirata, Y. Sato, T. Masuda, Preparation and optimization of mordenite nanocrystal-layered membrane for dehydration by pervaporation, Microporous And Mesoporous Materials, 207 (2015) 39-45.[7] D. Vargas-Hernandez, M.A. Perez-Cruz, R. Hernandez-Huesca, Selective adsorption of ethylene over ethane on natural mordenite and on K -exchanged mordenite, Adsorption-Journal Of the International Adsorption Society, 21 (2015) 153-163.[8] A. Said, T.J. Daou, L. Limousy, J. Bikai, J. Halwani, J. Toufaily, T. Hamieh, P. Dutournie, Surface energy modification of a Na-mordenite thin layer treated by an alkaline solution, Materials Express, 5 (2015) 451-456.[9] R. Ono, A. Ikeda, E. Matsuyama, M. Nomura, Permeation Evaluation of a Mordenite Zeolite Membrane by Using an Alkaline Post-Treatment, Journal Of Chemical Engineering Of Japan, 48 (2015) 444-449.[10] M.-H. Zhu, S.-L. Xia, X.-M. Hua, Z.-J. Feng, N. Hu, F. Zhang, I. Kumakiri, Z.-H. Lu, X.-S. Chen, H. Kita, Rapid Preparation of Acid-Stable and High Dehydration Performance Mordenite Membranes, Industrial Engineering Chemistry Research, 53 (2014) 19168-19174.[11] L. Limousy, P. Dutournie, E. Chevereau-Landais, Description of the preferential transport of monovalent salts through Na-mordenite membrane: Physico-chemical aspects, Microporous And Mesoporous Materials, 167 (2013) 133-136.[12] Y. Kawamura, Y. Iwai, K. Munakata, T. Yamanishi, Effect of cation exchange on hydrogen adsorption property of mordenite for isotope separation, Journal Of Nuclear Materials, 442 (2013) S455-S460.[13] M. Asghari, A. Hassanvand, T. Mohammadi, Fabrication and characterization of highly crystalline mordenite membranes on alpha-alumina disks via a seeded in situ template-free hydrothermal treatment, Adsorption-Journal Of the International Adsorption Society, 19 (2013) 903-908.[14] X. Ren, J. Yang, Z. Chen, X. Yang, J. Lu, Y. Zhang, J. Wang, Preparation and Performance of Mordenite Zeolite Membrane Using Fluoride Route, Chinese Journal Of Catalysis, 33 (2012) 1558-1564.[15] M. Fujiwara, Y. Fujio, Y. Sato, H. Sakurai, I. Kumakiri, An approach to the storage of molecular oxygen into mordenite micropore by modification with 1,4-bis(hydroxydimethylsilyl)benzene, Microporous And Mesoporous Materials, 155 (2012) 34-39.[16] Z. Chen, Y. Li, D. Yin, Y. Song, X. Ren, J. Lu, J. Yang, J. Wang, Microstructural optimization of mordenite membrane for pervaporation dehydration of acetic acid, Journal Of Membrane Science, 411 (2012) 182-192.[17] K. Sato, K. Sugimoto, T. Kyotani, N. Shimotsuma, T. Kurata, Synthesis, reproducibility, characterization, pervaporation and technical feasibility of preferentially b-oriented mordenite membranes for dehydration of acetic acid solution, Journal Of Membrane Science, 385 (2011) 20-29.[18] P. Dutournie, L. Limousy, N. Zouaoui, H. Mahzoul, E. Chevereau, Facilitated transport of monovalent salt mixture through ultrafiltration Na-Mordenite membrane: Numerical investigations of electric and dielectric contributions, Desalination, 280 (2011) 397-402.[19] Y.F. Zhang, Z.Q. Xu, Q.L. Chen, Synthesis of small crystal polycrystalline mordenite membrane, Journal Of Membrane Science, 210 (2002) 361-368.

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