1. 毕业设计（论文）的内容和要求
课题的基本要求：（1）通过查阅中英文文献，了解含超临界二氧化碳的二元体系在高压条件下相平衡情况的国内外研究现状；（2）学习和掌握高压相平衡实验装置的操作以及实验数据的分析方法；（3）测定不同温度、压力下超临界CO2与其他物质组成的二元体系的相平衡数据；（4）分析实验数据，得出结果，撰写毕业论文。
预计完成任务及时间：2020年6月3号
2. 参考文献
[1]. Khairutdinov, V.F., et al., Solubility of naphthaline in supercritical binary solvent propane plus n-butane mixture. JOURNAL OF SUPERCRITICAL FLUIDS, 2020. 156(104628). [2]. Tsivintzelis, I., S. Ali and G.M. Kontogeorgis, Modeling systems relevant to the biodiesel production using the CPA equation of state. Part 2. Systems with supercritical CO2. FLUID PHASE EQUILIBRIA, 2020. 504(112337). [3]. Alvarez, I., et al., Measurement, correlation and modelling of high-pressure phase equilibrium of PLGA solutions in CO2. JOURNAL OF SUPERCRITICAL FLUIDS, 2020. 155(UNSP 104637). [4]. Higgoda, U.A., et al., Fick diffusion coefficients of binary fluid mixtures consisting of methane, carbon dioxide, and propane via molecular dynamics simulations based on simplified pair-specific ab initio-derived force fields. FLUID PHASE EQUILIBRIA, 2019. 502(112257). [5]. Kloc, A.P., et al., Phase equilibrium measurements and thermodynamic modeling of {CO2 diethyl succinate plus cosolvent} systems. FLUID PHASE EQUILIBRIA, 2019. 502(112285). [6]. Fortunatti-Montoya, M., et al., Fractionation of glycerol acetates with supercritical CO2. JOURNAL OF SUPERCRITICAL FLUIDS, 2019. 153(UNSP 104575). [7]. Gong, H., et al., Effects of cosolvent on dissolution behaviors of PVAc in supercritical CO2: A molecular dynamics study. CHEMICAL ENGINEERING SCIENCE, 2019. 206: p. 22-30. [8]. Pilarova, V., et al., Extending the design space in solvent extraction - from supercritical fluids to pressurized liquids using carbon dioxide, ethanol, ethyl lactate, and water in a wide range of proportions. GREEN CHEMISTRY, 2019. 21(19): p. 5427-5436. [9]. Korosi, M., et al., New vapour-liquid equilibrium data on the ternary system carbon dioxide - methanol - dimethyl sulphoxide. FLUID PHASE EQUILIBRIA, 2019. 497: p. 133-139.[10]. Fourie, F.C.V.N., C.E. Schwarz and J.H. Knoetze, CO2 n-dodecane 1-decanol: High pressure experimental phase equilibria data and thermodynamic modelling. JOURNAL OF SUPERCRITICAL FLUIDS, 2019. 151: p. 49-62. [11]Wanderson R. Giacomin Junior,Claudia A. Capeletto,Fernando A. P. Voll,Marcos L. Corazza. （二氧化碳 乙酰丙酸乙酯）和（二氧化碳 乙酰丙酸）体系的相平衡测量和热力学模拟[J]. Journal of Chemical Engineering Data,2019.[12]Xiao-Qiang Bian,Wei Xiong,Don Thisal Kaushika Kasthuriarachchi,Yong-Bing Liu. 基于状态关联方程的二氧化碳在氯化钠水溶液中溶解度的相平衡模拟[J]. Industrial Engineering Chemistry Research,2019.
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