基于2,6-二氨基-3,5-二硝基吡嗪-1-氧化物的含能金属有机框架材料制备任务书

 2021-11-05 19:20:37

1. 毕业设计(论文)的内容和要求

1. 含能有机配体2,6-二氨基-3,5-二硝基吡嗪-1-氧化物的合成与表征(红外、核磁共振氢谱、碳谱);2. 基于2,6-二氨基-3,5-二硝基吡嗪-1-氧化物的配合物的制备及其表征(红外、粉末衍射、单晶衍射)3. 结果与讨论

2. 参考文献

1. P. C. Wang, Y. G. Xu, M. Lu, et al. Recent advances in the syntheses and properties of polynitrogen pentazolate anion cyclo-N5- and its derivatives. Chem. Soc. Rev., 2018, 47, 7522.2. Q. H. Zhang, J. M. Shreeve. Metal-organic frameworks as high explosives: a new concept for energetic materials. Angew. Chem. Int. Ed., 2014, 53, 2540.3. W. Q. Zhang, K. C. Wang, Q. H. Zhang, et al. Stabilization of the pentazolate anion in a zeolitic architecture with Na20N60 and Na24N60 nanocages. Angew. Chem. Int. Ed., 2018, 57, 2592.4. J. G. Xu, C. Sun, M. J. Zhang, et al. Coordination polymerization of metal azides and powerful nitrogen-rich ligand toward primary explosives with excellent energetic performances. Chem. Mater., 2017, 29, 9725.5. Q. Sun, X. Li, M. Lu., et al. Dancing with 5-substituted monotetrazoles, oxygen-rich ions, and silver: Towards primary explosives with positive oxygen balance and excellent energetic performance. J. Mater. Chem. A, 2019, 7, 4611.

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