全文总字数：9836字
1. 毕业设计（论文）的内容和要求
2. 实验内容和要求
IR,TG,EDS
3. 参考文献
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A.; Velmurugan, G.; Wilson, C.; Valiente, R.; Rajaraman, G.; Murrie, M. Magnetic Properties of a Family of [MnIII4LnIII4] Wheel Complexes: An Experimental and Theoretical Study. Inorg. Chem. 2019, 58, 13815-13825.(6) Zhang, Y. J.; Wu, G.; Xu, H.; Wang, X.; Long, L. S.; Kong, X. J.; Zheng, L. S. Magnetooptical Properties of Chiral [Co2Ln] Clusters. Inorg. Chem. 2020, 59, 193-197.(7) Zheng, Y.; Zhang, Q. C.; Long, L. S.; Huang, R. B.; Mtiller, A.; Schnack, J.; Zheng, L. S.; Zheng, Z. Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron coret. Chem. Commun. 2013, 49, 36-38.(8) Liu, D.-P.; Peng, J.-B.; Lin, X.-P.; Huang, Q.; Kong, X.-J.; Long, L.-S.; Huang, R.-B.; Zheng, L.-S. Myo-inositol supported heterometallic Dy24M2 (M = Ni, Mn) cages. CrystEngComm. 2014, 16, 5527-5530.(9) Guo, F. S.; Leng, J. D.; Liu, J. L.; Meng, Z. S.; Tong, M. L. Polynuclear and polymeric gadolinium acetate derivatives with large magnetocaloric effect. Inorg. Chem. 2012, 51, 405-413.(10) Liu, J. H.; Lin, L. D.; Wang, G. Q.; Li, L. Y.; Sun, Y. Q.; Li, X. X.; Zheng, S. T. All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters. Chem. Commun. 2020, 56, 10305-10308.(11) Peng, J. B.; Zhang, Q. C.; Kong, X. J.; Ren, Y. P.; Long, L. S.; Huang, R. B.; Zheng, L. S.; Zheng, Z. A 48-metal cluster exhibiting a large magnetocaloric effect. Angew. Chem., Int. Ed. 2011, 50, 10649-10652.(12) Chen, W. P.; Liao, P. Q.; Jin, P. B.; Zhang, L.; Ling, B. K.; Wang, S. C.; Chan, Y. T.; Chen, X. M.; Zheng, Y. Z. The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated "Star-of-David" for Photocatalytic CO2 Reduction and Magnetic Cooling. J. Am. Chem. Soc. 2020, 142, 4663-4670.(13) Qiao, W.-Z.; Xu, H.; Cheng, P.; Zhao, B. 3d-4f Heterometal朞rganic Frameworks for Efficient Capture and Conversion of CO2. Cryst. Growth Des. 2017, 17, 3128-3133.(14) Darii, M.; Kravtsov, V. C.; Kr鋗er, K.; Hauser, J.; Decurtins, S.; Liu, S.-X.; Affronte, M.; Baca, S. G. Aggregation of a Giant Bean-like {Mn26Dy6} Heterometallic Oxo-Hydroxo-Carboxylate Nanosized Cluster from a Hexanuclear {Mn6} Precursor. Cryst. Growth Des. 2019, 20, 33-38.(15) Chen, W. P.; Liao, P. Q.; Yu, Y.; Zheng, Z.; Chen, X. M.; Zheng, Y. Z. A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications. Angew. Chem., Int. Ed. 2016, 55, 9375-9379.(16) Chen, W. P.; Singleton, J.; Qin, L.; Camon, A.; Engelhardt, L.; Luis, F.; Winpenny, R. E. P.; Zheng, Y. Z. Quantum Monte Carlo simulations of a giant {Ni21Gd20} cage with a S = 91 spin ground state. Nat. Commun. 2018, 9, 1-6.(17) Chen, L.; Guo, J. Y.; Xu, X.; Ju, W. W.; Zhang, D.; Zhu, D. R.; Xu, Y. A novel 2-D coordination polymer constructed from high-nuclearity waist drum-like pure Ho48 clusters. Chem. Commun. 2013, 49, 9728-9730.(18) Lin, Q.; Li, J.; Dong, Y.; Zhou, G.; Song, Y.; Xu, Y. Lantern-shaped 3d-4f high-nuclearity clusters with magnetocaloric effect. Dalton Trans. 2017, 46, 9745-9749.(19) He, X.; Liu, Y.; Lv, Y.; Dong, Y.; Hu, G.; Zhou, S.; Xu, Y. L- and D-[LnZn(IN)3(C2H4O2)]n (Ln = Eu, Sm, and Gd): Chiral Enantiomerically 3D 3d-4f Coordination Polymers Constructed by Interesting Butterfly-like Building Units and -[Ln-O-Zn]n- Helices. Inorg. Chem. 2016, 55, 2048-2054.(20) Wen, H. R.; Hu, J. J.; Yang, K.; Zhang, J. L.; Liu, S. J.; Liao, J. S.; Liu, C. M. Family of Chiral ZnII-LnIII (Ln = Dy and Tb) Heterometallic Complexes Derived from the Amine-Phenol Ligand Showing Multifunctional Properties. Inorg. Chem. 2020, 59, 2811-2824.(21) Luo, X. M.; Hu, Z. B.; Lin, Q. F.; Cheng, W.; Cao, J. P.; Cui, C. H.; Mei, H.; Song, Y.; Xu, Y. Exploring the Performance Improvement of Magnetocaloric Effect Based Gd-Exclusive Cluster Gd60. J. Am. Chem. Soc. 2018, 140, 11219-11222.(22) Yang, X.; Schipper, D.; Jones, R. A.; Lytwak, L. A.; Holliday, B. J.; Huang, S. Anion-Dependent Self-Assembly of Near-Infrared Luminescent 24-and 32-Metal Cd-Ln Complexes with Drum-like Architectures. J. Am. Chem. Soc. 2013, 135, 8468-8471.(23) Zheng, X.-Y.; Jiang, Y.-H.; Zhuang, G.-L.; Liu, D.-P.; Liao, H.-G.; Kong, X.-J.; Long, L.-S.; Zheng, L.-S. A Gigantic Molecular Wheel of {Gd140}: A New Member of the Molecular Wheel Family. J. Am. Chem. Soc. 2017, 139, 1817818181.(24) Kong, X. J.; Ren, Y. P.; Chen, W. X.; Long, L. S.; Zheng, Z.; Huang, R. B.; Zheng, L. S. A four-shell, nesting doll-like 3d-4f cluster containing 108 metal ions. Angew. Chem., Int. Ed. 2008, 47, 2398-2401.(25) Zheng, Y. Z.; Evangelisti, M.; Winpenny, R. E. Large magnetocaloric effect in a Wells-Dawson type {Ni6Gd6P6} cage. Angew. Chem., Int. Ed. 2011, 50, 3692-3695.(26) Guo, F. S.; Chen, Y. C.; Liu, J. L.; Leng, J. D.; Meng, Z. S.; Vrabel, P.; Orendac, M.; Tong, M. L. A large cryogenic magnetocaloric effect exhibited at low field by a 3D ferromagnetically coupled MnII-GdIII framework material. Chem. Commun. 2012, 48, 12219-12221.(27) Kong, X. J.; Long, L. S.; Huang, R. B.; Zheng, L. S.; Harris, T. D.; Zheng, Z. A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped. Chem. Commun. 2009, 29, 4354-4356.(28) Leng, J.-D.; Liu, J.-L.; Tong, M.-L. Unique nanoscale {CuII36LnIII24} (Ln = Dy and Gd) metallo-rings. Chem. Commun. 2012, 48, 5286-5288.(29) Peng, J. B.; Zhang, Q. C.; Kong, X. J.; Zheng, Y.-Z.; Ren, Y. P.; Long, L.-S.; Huang, R.-B.; Zheng, L.-S.; Zheng, Z. High-Nuclearity 3d-4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets. J. Am. Chem. Soc. 2012, 134, 3314?317.(30) Li, N. F.; Lin, Q. F.; Luo, X. M.; Cao, J. P.; Xu, Y. Cl--Templated Assembly of Novel Peanut-like Ln40Ni44 Heterometallic Clusters Exhibiting a Large Magnetocaloric Effect. Inorg. 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A single-ligand-protected Eu60nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations. Inorg. Chem. Front. 2020, 7, 2072-2079.
4. 毕业设计（论文）计划
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