层状钒氧酸盐合成,表征及质子导电性质任务书

 2021-11-05 07:11

1. 毕业设计(论文)的内容和要求

层状钒氧酸盐是钒氧多面体通过共边或者共顶点的方式相互连接而形成,质子化有机阳离占据层间空间。

在高温下会表现出好的无水质子传导性质。

此外,在有湿度的条件下,水分子进入层间,与阴离子层的氧形成致密的氢键网络,质子可以在氢键网络上进行跳跃,使化合物表现出好的质子传导性能。

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2. 参考文献

1.J. Chen, L. Hu, J. Deng and X. Xing, Negative thermal expansion in functional materials: controllable thermal expansion by chemical modifications Chem. Soc. Rev., 2015, 44, 35223567.2.S. E. Tallentire, F. Child, I. Fall, L. Vella-Zarb, I. R. Evans, M. G. Tucker, D. A. Keen, C. Wilson and J. S. O. Evans,Systematic and Controllable Negative, Zero, and Positive Thermal Expansion in Cubic Zr1xSnxMo2O8 J. Am. Chem. Soc., 2013, 135, 1284912856.3.P. Lama, R. K. Das, V. J. Smith and L. J. Barbour, A combined stretchingtilting mechanism produces negative, zero and positive linear thermal expansion in a semi-flexible Cd(II)-MOF. Chem. Commun., 2014, 50, 64646467.4.E. J. Liang, Y. Liang, Y. Zhao, J. Liu and Y. Jiang, Low-Frequency Phonon Modes and Negative Thermal Expansion in A(MO4)2 (A = Zr, Hf and M = W, Mo) by Raman and Terahertz Time-Domain Spectroscopy. J. Phys. Chem. A, 2008, 112, 1258212587.5.L. Hu, J. Chen, L. L. Fan, Y. Ren, Y. C. Rong, Z. Pan, J. X. Deng, R. B. Yu and X. R. Xing, Zero Thermal Expansion and Ferromagnetism in Cubic Sc1xMxF3 (M = Ga, Fe) over a Wide Temperature Range. J. Am. Chem. Soc., 2014, 136, 13566-13569.6.X. Y. Song, Z. H. Sun, Q. Huang, M. Rettenmayr, X. M. Liu, M. Seyring, G. N. Li, G. H. Rao and F. X. Yin, Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride. Adv. Mater., 2011, 23, 4690-4694.7.S. Margadonna, K. Prassides, and A. N. Fitch, Zero Thermal Expansion in a Prussian Blue Analogue. J. Am. Chem. Soc., 126, 15390-15391.8.J. O. Ticknor, B. R. Hester, J. W. Adkins, W. Xu, A. A. Yakovenko and A. P. Wilkinson, Zero Thermal Expansion and Abrupt Amorphization on Compression in Anion Excess ReO3Type Cubic YbZrF7. Chem. Mater., 2018, 30, 3071-3077.9.V. Mishra, U. Subbarao, S. Roy, S. C. Sarma, D. Mumbaraddi, S. Sarkar and S. C. Peter, Anisotropic Near-Zero Thermal Expansion in REAgxGa4x (RE = LaNd, Sm, Eu, and Yb) Induced by Structural Reorganization, Inorg. Chem., 2018, 57, 12576-12587. 10.J. S. O. Evans, T. A. Mary, T. Vogt, M. A. Subramanian and A. W. Sleight, Negative Thermal Expansion in ZrW2O8 and HfW2O8, Chem. Mater., 1996, 8, 2809-2823.11.A. E. Phillips, A. L. Goodwin, G. J. Halder, P. D. Southon and C. J. Kepert, Nanoporosity and Exceptional Negative Thermal Expansion in Single-Network Cadmium Cyanide, Angew. Chem. Int. Ed., 2008, 47, 13961399.12.A. K. A. Pryde, K. D. Hammonds, M. T. Dove, V. Heine, J. D. Gale and M. C. Warren, Origin of the negative thermal expansion in ZrW2O8 and ZrV2O7. J. Phys. Condens. Matter, 1996, 8, 1097310982.13.F. Bridges, T. Keiber, P. Juhas, S. J. L. Billinge, L. Sutton, J. Wilde and G. R. Kowach, Local Vibrations and Negative Thermal Expansion in ZrW2O8, Phys. Rev. Lett., 2014, 112, 045505.14.C. R. Morelock, B. K. Greve, M. Cetinkol, K. W. Chapman, P. J. Chupas and A. P. Wilkinson, Role of Anion Site Disorder in the Near Zero Thermal Expansion of Tantalum Oxyfluoride, Chem. Mater., 2013, 25, 19001904.15.S. S. Han and W. A. Goddard III, Metal-Organic Frameworks Provide Large Negative Thermal Expansion Behavior, J. Phys. Chem. C, 2007, 111, 1518515191.16.K. Takenaka and H. Takagi, Giant negative thermal expansion in Ge-doped anti-perovskite manganese nitrides Appl. Phys. Lett., 2005, 87, 261902.17.P. Miao, X. Lin, A. Koda, S. Lee, Y. Ishikawa, S. Torii, M. Yonemura, T. Mochiku, H. Sagayama, S. Itoh, K. Ikeda, T. Otomo, Y. Wang, R. Kadono and T. Kamiyama, Large Magnetovolume Effect Induced by Embedding Ferromagnetic Clusters into Antiferromagnetic Matrix of Cobaltite Perovskite, Adv. Mater., 2017, 29, 1605991.

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