聚(2,5-呋喃二甲酸乙二醇酯-co-丁二酸乙二醇酯)的合成任务书

 2021-10-01 22:07:36

1. 毕业设计(论文)的内容和要求

内容:(1) 查阅文献。

(2) 购买乙二醇、丁二酸、2,5-呋喃二甲酸(FDCA)、催化剂等。

(3) 以2-5呋喃二甲酸、乙二醇、丁二酸为主要底物,加入催化剂,利用直接酯化法先分别生成呋喃二甲酸乙二醇酯(EF)和丁二酸乙二醇酯(ES)。

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2. 参考文献

[1]Binder J B,Raines R T.Simple chemical transformation of lignocellulosic biomass into furans for furls and chemicals[J].J Am Chem Soc,2009.131(5):1979一1985.[2]沈四和. 甘油氢解制二元醇镍基催化剂的研究. 厦门大学硕士学位论文.2009-6-1[3] M. Bicker, J. Hirth , H. Vogel. Dehydration of fructose to 5-hydroxymethylfurfural in sub-and supercritical acetone[J].Green Chem.2003,5(2):280-284 [4] J. B. Binder, R. T. Raines. Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals[J].J AM CHEM SOC.2009,131(5):19791985[5] T.E. Hajj, A. Masroua, J. C. Martin, G. Descotes. Synthesis of 5-(hydroxymethyl)-furan-2-carboxaldehyde and its derivatives by acid treatment of sugars on ion-exchange resins[J].Bull.Soc.Chim.Fr.1987,855-860[6]L. Cottier, G. Descotes, J. Lewkowski, R. Skowronski. Oxidation of 5-Hydroxy-methylfurfural under Sonochemical Conditions[J].Polish Journal of Chemistry Pol.J.Chem.1994,68(4):693-698[7]G. Grabowski, J. Lewkowski, R .Skowronski. Synthesis, chemistry and applications of 5-hydroxymethylfurfural[P].PL Patent 161831,1990.[8]G. Grabowski, J. Lewkowski, R. Skowronski. Electrochemical Oxidation of 5-Hydroxymethylfurfural with the Nickel Oxide/Hydroxide Electrode[J].Electrochim. Acta 1991,36(13):1995-1995[9] Lew, B. V.Neue Polyamide aus niedermolekularen Kohlenhydraten: Darstellung und Polykondensation von Monomerbausteinen aus Saccharose,D-Glucose,D-Fructose, D-Galactose und Isomaltulose[P].US Patent 3326944,1968.[10]Leupold, E. I., Wiesner. M., Schlingmann. Towards improving the utility of ketoses asorganic raw materials[P].DE.3.826.073[11] P. Vinke, H. H.Van Dam, H.V an Bekkum. New Developments in Selective Oxidation[J].Stud.Surf.Sci.Catal.1990,55:147-158[12] Y. Y. Gorbanev,S. K. Klitgaard, etal. Gold-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural in Water at Ambient Temperature[J].ChemSusChem.2009,2(7):672-675[13]M.L.Ribeiro,U.Schuchardt.Cooperative effect of cobalt acetylacetonate and silica in thecatalytic cyclization and oxidation of fructose to2,5-furandicarboxylic acid[J].Catal. Commun.2003,4(2):8386[14]Gandini A. Polymers from renewable resources: A challenge for the future of macromolecular materials. Macromolecules, 2008, 41 (24): 9491~9504.[15] 周广远 姜敏 张强 叶冲 .聚2,5-呋喃二甲酸乙二醇酯及其制备方法.中华人民共和国国家知识产权局. 2011-9-21

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