Eu3 与1,4-苯二甲酸配位聚合物的制备与表征任务书

 2021-11-05 07:11

1. 毕业设计(论文)的内容和要求

配位聚合物具有多种多样的结构,而且在荧光、磁性、气体吸附与分离和荧光探针等领域具有潜在的应用。

在众多配位聚合物中,稀土离子由于具有特殊的荧光特性而被广泛应用于全色荧光材料、荧光传感器等领域。

铕是最稀有的稀土元素,可用作彩色电视机的荧光粉,在激光材料等领域有重要的应用。

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2. 参考文献

[1]MetalOrganic Frameworks with Target-Specific Active Sites Switched by Photoresponsive Motifs: Efficient Adsorbents for Tailorable CO2 Capture. 2019.[2]Li, H. Liu, H. B. etal,.Single component tri-rare-earth emitting MOF for warm white light LEDs. Dalton TransactionsNovel, 2018.47(25): p. 8427-8433.[3] Mahata, P., et al., Luminescent rare-earth-based MOFs as optical sensors. Dalton Transactions, 2017. 46(2): p. 301-328.[4]Silva, I. G. N. Cunha, C. S. etal, Eu3 or Sm3 -Doped terbium-trimesic acid MOFs: Highly efficient energy transfer anhydrous luminophors,Optical Materials, 2018,84: p.123-129[5]Mahata, P., et al., Luminescent rare-earth-based MOFs as optical sensors. Dalton Transactions, 2017. 46(2): p. 301-328.[6]Pan, H. Xu, S. Ni, Y. H.Rare-earth post-modified Zn-based coordination polymer microspheres: Simple room-temperature preparation, fluorescent performances and application for detection of tryptophane. Sensors and Actuators B-Chemical, 2019,283:p.731-739.[7]Yang, S. L. Wang, R. R. etal. Four new rare-earth nitronyl nitroxide radical complexes: Magnetic and luminescent properties, Polyhedron, 2018,144: p101-106.[8]Zhang, X. D. Li, B. etal.Metal-Organic Frameworks Modulated by Doping Er3 for Up-Conversion Luminescence. Acs Applied Materials Interfaces, 2016, 8(27): p.17389-17394.[9] Zhang, L. L.Yuan, S. etal.Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks. Angewandte Chemie-International Edition, 2018,57(18): p.5095-5099.[10] Binh, N. T.Tien, D. M. etal.Study on preparation and characterization of MOF based lanthanide doped luminescent coordination polymers. Materials Chemistry and Physics, 2014,143(3):p.946-951.[11]Silva, I.G.N., et al., Highly luminescent Eu3 -doped benzenetricarboxylate based materials. Journal of Luminescence, 2016. 170: p. 364-368.

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