微尺度下可见光介导的1,7-烯炔类化合物的三氟甲基化反应任务书

 2021-10-23 08:10

1. 毕业设计（论文）的内容和要求

通过文献调研初步掌握利用可见光催化的反应机理与反应类型；另一方面查阅涉及利用可见光实现三氟甲基化反应相关文献，归纳反应体系，为后期实验操作打下基础。

2. 参考文献

[1] For selected reviews describing the benefits of fluorine incorporation in drug structures: a) Y. Zhou, J. Wang, Z. Gu, S. Wang, W. Zhu, J. L. Acena, V. A. Soloshonok, K. Izawa, H. Liu, Chem. Rev. 2016, 116, 422?18; b) S. Purser, P. R. Moore, S. Swallow, V. Gouverneur, Chem. Soc. Rev. 2008, 37, 320 ?30; c) K. Mueller, C. Faeh, F. Diederich, Science 2007, 317, 1881?886.[2] Reviews on trifluoromethylations: (a) Nie, J.; Guo, H.-C.; Cahard, D.; Ma, J.-A. Chem. Rev. 2011, 111, 455. (b) Liu, X.; Xu, C.; Wang, M.; Liu, Q. Chem. Rev. 2015, 115, 683. (c) Charpentier, J.; Fruh, N.; Togni, A. Chem. Rev. 2015, 115, 650. (d) Tomashenko, O. A.; Grushin, V. V. Chem. Rev. 2011, 111, 4475. (e) Chu, L.; Qing, F.-L. Acc. Chem. Res. 2014, 47, 1513. (f) Liang, T.; Neumann, C. N.; Ritter, T. Angew. Chem., Int. Ed. 2013, 52, 8214. (g) Liu, H.; Gu, Z.; Jiang, X. Adv. Synth. Catal. 2013, 355, 617. (h) Mace? Y.; Magnier, E. Eur. J. Org. Chem. 2012, 2479. (i) Wu, X.-F.; Neumann, H.; Beller, M. Chem.Asian J. 2012, 7, 1744.[3] Examples of radical trifluoromethylation: (a) Studer, A. Angew. Chem., Int. Ed. 2012, 51, 8950. (b) Tomita, R.; Yasu, Y.; Koike, T.; Akita, M. Angew. Chem., Int. Ed. 2014, 53, 7144. (c) Deb, A.; Manna, S.; Modak, A.; Patra, T.; Maity, S.; Maiti, D. Angew. Chem., Int. Ed. 2013, 52, 9747. (d) Zhu, R.; Buchwald, S. L. Angew. Chem., Int. Ed. 2013, 52, 12655. (e) Jiang, X.-Y.; Qing, F.-L. Angew. Chem., Int. Ed. 2013, 52, 14177. (f) Ye, Y.; Sanford, M. S. J. Am. Chem. Soc. 2012, 134, 9034. (g) Mizuta, S.; Verhoog, S.; Engle, K. M.; Khotavivattana, T.; O扗uill, M.; Wheelhouse, K.; Rassias, G.; Me靌ebielle, M.; Gouverneur, V. J. Am. Chem. Soc. 2013, 135, 2505. (h) Zhang, B.; Studer, A. Org. Lett. 2014, 16, 3990. (i) Ye, Y.; Kunzi, S. A.; Sanford, M. S. Org. Lett. 2012, 14, 4979. (j) Xin, J.; Yuan, X.; Abdukader, A.; Zhu, J.; Ma, J. Org. Lett. 2014, 16, 1768.[4] For recent reviews on visible light photoredox catalysis, see: (a) Yoon, T. P.; Ischay, M. A.; Du, J. Nat. Chem. 2010, 2, 527. (b) Narayanam, J. M. R.; Stephenson, C. R. J. Chem. Soc. Rev. 2011, 40, 102. (c) Allen, A. E.; MacMillan, D. W. C. Chem. Sci. 2012, 3, 633. (d) Shi, L.; Xia, W. Chem. Soc. Rev. 2012, 41, 7687. (e) Xuan, J.; Xiao, W.-J. Angew. Chem., Int. Ed. 2012, 51, 6828. (f) Prier, C. K.; Rankic, D. A.; MacMillan, D. W. C. Chem. Rev. 2013, 113, 5322. (g) Hari, D. P.; Konig, B. Chem. Commun. 2014, 50, 6688. (h) Nicewicz, D. A.; Nguyen, T. M. ACS Catal. 2014, 4, 355.

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