1. 毕业设计（论文）的内容和要求
1. 查阅、整理文献资料，加深对课题的理解，并撰写开题报告。
2. 要求学生对分离工程、有机化学、无机与分析化学、仪器分析等学科复习，从而对以后催化性能测试实验、谱图分析打下基础。
3. 主要研究通过不同种类的单体通过超交联进行合成，并用XRD、FT-IR、SEM电镜等表征手段进行表征。
2. 参考文献
[1]Ya Gao,Yuan Gao,Lei Shi,Qi Sun. Hydrothermal Glucose Modified C/V-SiO 2 as a Reusable Heterogeneous Catalyst for Benzene Oxidation to Phenol by O 2[J]. Catalysis Letters,2017,147(11).[2]高肖汉. 苯环羟基化催化剂的研究[D].中国科学院研究生院（大连化学物理研究所）,2006.[3]唐皓. 氧气苯制苯酚的催化剂制备及其催化性能研究[D].陕西科技大学,2019.[4]周仕林,邹峰,顾颖颖.含铁模拟酶催化苯羟基化反应[J].过程工程学报,2009,9(06):1085-1089.[5]李宏峰,伏再辉,尹笃林.Pd-V/Hβ催化苯与氢气、氧气直接羟基化制取苯酚[J].湖南师范大学自然科学学报,2006(03):61-64.[6]闫肃,万荫松,李国轲,吕雪川,高肖汉.苯羟基化合成苯酚的研究进展[J].化学世界,2014,55(05):301-306 320.[7]王伟涛,姚敏,马养民,张金.氧气直接氧化苯制备苯酚[J].化学进展,2014,26(10):1665-1672.[8]Weitao Wang,Na Li,Leilei Shi,Yangmin Ma,Xiufang Yang. Vanadium-zirconium catalyst on different support for hydroxylation of benzene to phenol with O2 as the oxidant[J]. Applied Catalysis A, General,2018,553.[9]Shili Shu, Yan Huang,* Xiaojuan Hu, Yiqun Fan, and Nanping Xu .On the Membrane Reactor Concept for One-Step Hydroxylation of Benzene to Phenol with Oxygen and Hydrogen .J. Phys. Chem. C 2009, 113, 45, 19618-19622[10]Zhouyang Long, Yadong Zhang,Guojian Chen*, Jiang Shang,Yu Zhou, Jun Wang, and Liming Sun*, Nitrogen-Doped Biomass Carbons Meet with Polyoxometalates: Synergistic Catalytic Reductant-Free Aerobic Hydroxylation of Benzene to Phenol .ACS Sustainable Chem. Eng. 2019, 7, 4, 4230-4238[11]Shankha Shubhra Acharyya,Shilpi Ghosh,Ritesh Tiwari,Chandrashekar Pendem,Takehiko Sasaki, and Rajaram BalSynergistic Effect between Ultrasmall Cu(II) Oxide and CuCr2O4 Spinel Nanoparticles in Selective Hydroxylation of Benzene to Phenol with Air as Oxidant .ACS Catal. 2015, 5, 5, 2850-2858[12]Jie Zhu, Guoqing Li, Qian Wang, Yu Zhou,* and Jun Wang*.Engineering Surface Groups of Commercially Activated Carbon for Benzene Hydroxylation to Phenol with Dioxygen.Ind. Eng. Chem. Res. 2019, 58, 44, 20226-20235[13]Sotaro Ito," Toshimichi Yamasaki, Hiroshi Okada, Susumu Okino, and Kazuo Sasaki ,Oxidation of benzene to phenols with molecular oxygen promoted by copper(I) chloride.J. Chem. Soc., Perkin Trans. 2, 1988, 285-293[14]Rei Hamada,a Yusuke Shibata,b Satoru Nishiyamab and Shigeru Tsuruya*,One-step gas-phase catalytic oxidation of benzene to phenol with molecular oxygen over Cu-supported ZSM-5 zeolites.Phys. Chem. Chem. Phys., 2003,5, 956-965[15]Thuan Duc Bui, Akira Kimura,Shigeru Ikeda,and Michio Matsumura*,Determination of Oxygen Sources for Oxidation of Benzene on TiO2 Photocatalysts in Aqueous Solutions Containing Molecular Oxygen.J. Am. Chem. Soc. 2010, 132, 24, 8453-8458[16]Shingo SumimotoChiaki TanakaSho-ta YamaguchiYuichi IchihashiSatoru NishiyamaShigeru Tsuruya,Zinc Powder as an Effective Reducing Reagent during Liquid-Phase Oxidation of Benzene to Phenol Using Molecular. Oxygen over V-Substituted Heteropoly Acid Catalysts.Ind. Eng. Chem. Res. 2006, 45, 22, 7444-7450[17]D R Lovley, J D Coates, J C Woodward, E Phillips.Benzene oxidation coupled to sulfate reduction.Applied and Environmental Microbiology Mar 1995, 61 (3) 953-958; DOI:[18]M. Bonchio, V. Conte, F. Di Furia,* and G. Modena*.Metal catalysis in oxidation by peroxides. 31. The hydroxylation of benzene by VO (O2)(PIC)(H2O) 2: mechanistic and synthetic aspects. J. Org. Chem. 1989, 54, 4368-4371[19]Mizuki Tada,Rajaram Bal,Takehiko Sasaki,Yohei Uemura,Yasuhiro Inada,Satoka Tanaka,Masaharu Nomura, and Yasuhiro Iwasawa*.Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O2: Performance and Reaction Mechanism.J. Phys. Chem. C 2007, 111, 27, 10095-10104[20]Guodong Wen, Shuchang Wu,BoL i, Chunli Dai, and Dang Sheng Su*.ActiveSites and Mechanisms for Direct Oxidation of Benzene to Phenol over Carbon Catalysts.Angew .Chem. Int.Ed. 2015, 54,41054109 [21]Wanjian Shan, Shuai Li, Xiaochun Cai,Jie Zhu, Yu Zhou,*and Jun Wang*.Carbon Catalyzed Hydroxylation of Benzene with Dioxygen to Phenol over Surface Carbonyl Groups.ChemCatChem 2019, 11, 10761085 [22]Weitao Wang,*Hao Tang a, Xulu Jiang a, Fu-E Huang a and Yangmin Ma* .Quinone-amine polymer as the metal-free and reductant-free catalyst for hydroxylation of benzene to phenol with molecular oxygen.Chem. Commun., 2019,55, 7772-7775[23]Weitao Wang, Guodong Ding, Tao Jiang,* Peng Zhang, Tianbin Wu and Buxing Han.Facile one-pot synthesis of VxOy@C catalysts using sucrose for the direct hydroxylation of benzene to phenol.Green Chem., 2013, 15, 1150[24]Qinhong Wei,hualin Fan,Fangfang Qin,Qingxiang Ma,Wenzhong Shen*.Metal-free honeycomb-like porous carbon as catalyst for direct oxidation of bezene to phenol.Carbon 133(2018)6-13[25]Weitao Wang*,Hao Tang,Xulu Jiang,Fu-E Huanga and Yangmin Ma*.Quinone-amine polymers as metal-free and reductant-free catalysts for hydroxylation of benzene to phenol with molecular oxygen.
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