1. 毕业设计（论文）的内容和要求
本课题将采用环氧树酯为基体，采用呋喃环与马来酰亚胺基团之间的可逆反应机理，赋予聚氨酯涂层热可逆自修复的性能。
首先通过KH560与N-氨基甲酰马来酰亚胺反应再经水解形成端基为马来酰亚胺基团的超支化结构，再通过与环氧树脂和糠胺的反应引入DA可逆键实现涂层材料自修复。
最后把整个研究内容写成毕业论文。
2. 参考文献
根据毕业要求指点10.2，毕设期间要进行研究现状调查与总结，要求在开题报告及毕业设计（论文）中涉及的英文文献不少于20篇，其中近5年不少于8篇，英文文献不少于5篇。
以下是与本课题相关的部分文献列表： [1] 赵翰文, 冯利邦, 史雪婷, et al. 热可逆自修复环氧树脂的合成与修复行为[J]. 高分子学报, 2018. [2] 童晓梅, 郝芹芹, 闫子英, et al. 硅烷改性环氧树脂自修复微胶囊的制备及应用[J]. 化工进展, 2018(9). [3] 廖乐平, 张伟, 赵阳. 仿生自修复环氧树脂涂层制备及性能[J]. 中国表面工程, 2013, 26(4):88-93. [4] 赵翰文, 冯利邦, 史雪婷, et al. 热可逆自修复环氧树脂的合成与修复行为[J]. 高分子学报, 2018.[5] 董培林. SiO2微球负载BTA缓蚀剂型自修复耐蚀涂层的制备及性能研究[J]. 表面技术, 2016, 45(3):158-163.[6] ZHANG F, JU P, PAN M, et al. Self-healing mechanisms in smart protective coatings: A review[J]. Corrosion Science, 2018, 144: 74-88. [7] HIA I L, VAHEDI V, PASBAKHSH P. Self-Healing Polymer Composites: Prospects, Challenges, and Applications[J]. Polymer Reviews, 2016, 56(2): 225-261.[8] BEKAS D G, TSIRKA K, BALTZIS D, et al. Self-healing materials: A review of advances in materials, evaluation, characterization and monitoring techniques[J]. Composites Part B: Engineering, 2016, 87: 92-119.[9] HANSEN C J, WU W, TOOHEY K S, et al. Self-Healing Materials with Interpenetrating Microvascular Networks[J]. Advanced Materials, 2009, 21(41): 4143-4147. [10] TOOHEY K S, HANSEN C J, LEWIS J A, et al. Delivery of Two-Part Self-Healing Chemistry via Microvascular Networks[J]. Advanced Functional Materials, 2009, 19(9): 1399-1405. [11] WHITE S R, SOTTOS N R, GEUBELLE P H, et al. Autonomic healing of polymer composites[J]. Nature, 2001, 409(6822): 794-797.[12] CHEN X, DAM M A, ONO K, et al. A Thermally Re-mendable Cross-Linked Polymeric Material[J]. Science, 2002, 295(5560): 1698-1702. [13]MIYAMAE K, NAKAHATA M, TAKASHIMA Y, et al. Self-Healing, Expansion-Contraction, and Shape-Memory Properties of a Preorganized Supramolecular Hydrogel through Host-Guest Interactions[J]. Angew Chem Int Ed Engl, 2015, 54(31): 8984-8987.[14] MURPHY E B, WUDL F. The world of smart healable materials[J]. Progress in Polymer Science, 2010, 35(1-2): 223-251.[15] WOJTECKI R J, MEADOR M A, ROWAN S J. Using the dynamic bond to access macroscopically responsive structurally dynamic polymers[J]. Nat Mater, 2011, 10(1): 14-27.[16] ZHANG P, LI G. Advances in healing-on-demand polymers and polymer composites[J]. Progress in Polymer Science, 2016, 57: 32-63. [17] CORDIER P, TOURNILHAC F, SOULIE-ZIAKOVIC C, et al. Self-healing and thermoreversible rubber from supramolecular assembly[J]. Nature, 2008, 451.[18] RODRIGUEZ E D, LUO X, MATHER P T. Linear/network poly(epsilon-caprolactone) blends exhibiting shape memory assisted self-healing (SMASH)[J]. ACS applied materials interfaces, 2011, 3(2): 152-161.
