光诱导接枝改性P(VDF-TrFE-CTFE)任务书

 2022-01-16 06:01

全文总字数:3557字

1. 毕业设计(论文)的内容和要求

太阳能由于具有清洁、可再生、且光谱范围广等的特点使之成为极具实用价值的新能源。

光伏行业的蓬勃发展对太阳能电池背膜的要求不断提高,光伏电池的效率随温度的升高而下降,在太阳能背膜上覆盖降温涂层可以有效的降低电池温度。

然而太阳能背膜材料多为PVDF基材料,表面能低,难以与其他功能涂层进行良好的粘接,因此发展PVDF基粘接材料,对提高太阳能电池效率、提高对清洁能源的利用具有重要意义。

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2. 实验内容和要求

1. 有机化学基本实验操作。

学习并掌握试剂的提纯、玻璃仪器的使用和清洗、磁力搅拌器和旋转蒸发仪等科学仪器的使用和维护等。

2. Schlenk无水无氧技术。

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3. 参考文献

1. A S A M, A S S, A S B,B B A. Macromolecular engineering approach for the preparation of new architectures from fluorinated olefins and their applications[J]. Progress in Polymer Science, 2020, 106.2. Qi Y, Wang Y, Zhao C, Ma Y,Yang W. Photo-graft modification of fluoropolymer surface and its bonding properties with EVA hot melt adhesive[J]. Chinese Science Bulletin, 2018, 63 (34).3. Kim K-H, Jung H-B, Lim J-H, Ji S-Y, Choi D H,Jeong D-Y. Configurational approach to the enhancement of the dielectric properties and energy density of polyvinylidene fluoride-based polymer composites[J]. Journal of Physics D: Applied Physics, 2020, 53 (37).4. Zhu Y, Jiang P,Huang X. Poly(vinylidene fluoride) terpolymer and poly(methyl methacrylate) composite films with superior energy storage performance for electrostatic capacitor application[J]. Composites Science and Technology, 2019, 179: 115-124.5. Guan F, Wang J, Yang L, Tseng J-K, Han K, Wang Q,Zhu L. Confinement-Induced High-Field Antiferroelectric-like Behavior in a Poly(vinylidene fluoride-co-trifluoroethylene-co-chlorotrifluoroethylene)-graft-polystyrene Graft Copolymer[J]. Macromolecules, 2011, 44 (7): 2190-2199.6. Liu J, Liao J, Liao Y, Zhang Z. High field antiferroelectric-like dielectric of poly(vinylidenefluoride-co-trifluoroethylene-co-chlorotrifluoroethylene)-graft-poly(styrene-methyl methacrylate) for high pulse capacitors with high energy density and low loss[J]. Polymer Chemistry, 2019, 10.7. Xin H, Guopeng C, Ning Z, Jinglin Z,Kai G. Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN[J]. Polymers, 2018, 10 (1): 68.8. A S A M, A S S, A S B,B B A. Macromolecular engineering approach for the preparation of new architectures from fluorinated olefins and their applications[J]. Progress in Polymer Science, 2020, 106.9. Hu X, Cui G, Zhang Y, Zhu N,Guo K. Copper(II) photoinduced graft modification of P(VDF- co -CTFE)[J]. European Polymer Journal, 2018: S0014305717317743.10. Xie H, Wang L, Gao X, Luo H, Liu L,Zhang D. High Breakdown Strength and Energy Density in Multilayer-Structured Ferroelectric Composite[J]. ACS Omega, 2020, 5 (50): 32660-32666.

4. 毕业设计(论文)计划

2020.122021.01 确定毕业设计题目2021.012021.02. 查阅文献、文献综述与开题2021.022021.03 基本实验技能学习和训练2021.032021.05 主体实验2021.052021.06 数据整理、撰写毕业论文和答辩

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