1. 毕业设计(论文)的内容和要求
(1)要求学生具有一定的化工原理、化工传递、化工热力学、物理化学、化工机械和分析表征的理论基础以及实践动手和独立的数据分析处理能力,并且对所学专业知识能够综合运用,可以独立进行文献检索,查阅资料解决问题。
(2) 本课题研究ZIF-8材料的固相合成工艺,并将其应用于轻石脑油中的正戊烷/异戊烷的吸附分离过程。
轻石脑油是以C4~C6饱和烷烃为主的馏分油,目前主要用于车用燃料汽油调配和用作乙烯裂解原料。
2. 参考文献
[1] 李雪琴, 曹利, 于胜楠, 等. 石脑油高效资源化研究进展[J]. 化工学报, 2015, 66(9):3287-3295.[2] Silva J A C, Rodrigues A E. Sorption and diffusion of n-pentane in pellets of 5A zeolite[J]. Industrial organic frameworks[J]. Chemical Society Reviews, 2009, 38(5): 1477-1504.[4] Furukawa H, Ko N, Go Y B, et al. Ultrahigh porosity in metal-organic frameworks[J]. Science, 2010, 329(5990):424-428.[5] Park K S, Ni Z, Ct A P, et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J]. Proceedings of the National Academy of Sciences, 2006, 103(27): 10186-10191.[6] Mendes P A, Rodrigues A E, Horcajada P, et al. Single and multicomponent adsorption of hexane isomers in the microporous ZIF-8[J]. Microporous owski K, Justyniak I, et al. A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors[J]. Chemical Communications, 2015, 51(19):4032-4035.[10] Uarevi K, Wang T C, Moon S Y, et al. Mechanochemical and solvent-free assembly of zirconium-based metalorganic frameworks[J]. Chemical Communications, 2016, 52(10):2133-2136.[11] Tanaka S, Kida K, Nagaoka T, et al. Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework [J]. Chem Commun, 2013, 49(72): 7884-7886.
