酸性离子液体在生物质平台分子转化中的性能探索任务书

 2021-10-24 03:10

1. 毕业设计(论文)的内容和要求

1. 查阅、整理文献资料,加深对自己课题的理解,并撰写开题报告。

2. 要求学生对分离工程、无机与分析化学、仪器分析等学科复习,从而对以后催化性能测试实验、谱图分析打下基础。

3. 主要研究由糖类酸水解生成重要平台化合物的生物质反应,根据反应需要选择合适的酸性离子液体作为催化剂尝试相关反应。

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2. 参考文献

[1]R. Otomo, T. Yokoi, J.N. Kondo, T. Tatsumi, Dealuminated Beta zeolite as effectivebifunctional catalyst for direct transformation of glucose to 5-hydroxymethylfurfural, Appl. Catal. A 470 (2014) 318326.[2] Huber. G. W, Iborra. S, Corma. A, Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering. Chem. Rev. 10 (2006) 40444098.[3] Brandt. A, Grasvik. J, Hallett. J. P,Welton. T, Deconstruction of lignocellulosic biomass with ionic liquids. Green Chem. 15 (2013)550583.[4] Li. C, Zhang. Z, Zhao. Z. K, Direct conversion of glucose and cellulose to 5-hydroxymethylfurfural in ionic liquid under microwave irradiation. Tetrahedron Lett. 50(2009) 54035405.[5]H. Li, Q. Zhang, X. Liu, F. Chang, Y. Zhang, W. Xue, S. Yang, Immobilizing Cr3 with SO3H-functionalized solid polymeric ionic liquids as efficient and reusable catalysts for selective transformation of carbohydrates into 5-hydroxymethylfurfural, Bioresour. Technol. 144 (2013) 21-27. [6] N. A. S. Ramli, N. A. S. Amin, A new functionalized ionic liquid for efficient glucose conversion to 5-hydroxymethyl furfural and levulinic acid, J. Mol. Catal. A: Chem. 407 (2015) 113-121. [7] W. Weiqi, W. Shubin, Experimental and kinetic study of glucose conversion to levulinic acid catalyzed by synergy of Lewis and Bronsted acids, Chem. Eng. J. 307 (2017) 389-398.[8] Y. Qu, C. Huang, Y. Song, J. Zhang, B. Chen, Efficient dehydration of glucose to 5-hydroxymethylfurfural catalyzed by the ionic liquid, 1-hydroxyethyl-3-methylimidazolium tetrafluoroborate, Bioresour. Technol. 121 (2012) 462-466.[9] F. Chambon, F. Rataboul, C. Pinel, A. Cabiac, E. Guillon, N. Essayem, Cellulose hydrothermal conversion promoted by heterogeneous Bronsted and Lewis acids: remarkable efficiency of solid Lewis acids to produce lactic acid, Appl. Catal. B 105 (2011) 171-181.[10]J. Zhang, Y. Cao, H. Li, X. Ma, Kinetic studies on chromium-catalyzed conversion of glucose into 5-hydroxymethylfurfural in alkylimidazolium chloride ionic liquid, Chem. Eng. J. 237 (2014) 55-61.

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