全文总字数：4426字
1. 毕业设计（论文）的内容和要求
1.掌握相关检索方法并查阅相关文献，并对相关文献的进行总结; 2.树立实验室安全卫生意识，培养良好的实验操作习惯; 3.理解甲烷芳构化反应过程，并掌握相关装置的使用方法; 4.掌握膜反应实验操作技能，了解相关表征手段，详尽客观记录实验数据并做相关分析； 5.学习相关处理软件并掌握实验数据处理方法; 6.按照规范书写毕业论文，并认真准备答辩.
2. 实验内容和要求
实验内容： 1.测试Mo/HZSM-5催化剂固定床反应性能； 2、掌握甲烷芳构化膜反应器的组装和流程； 3、测试MFI填充床膜反应器用于甲烷芳构化反应的性能。
基本要求： 1.严格遵守实验室安全规章制度，认真规范完成本科毕业论文设计； 2.能够熟练掌握膜反应操作过程； 3.考察催化剂装填量、反应温度等条件对甲烷芳构化反应性能的影响。
3. 参考文献
1.Lim, T. H.; Nam, K.; Song, I. K.; Lee, K.-Y.; Kim, D. H., Effect of Si/Al2 ratios in Mo/H-MCM-22 on methane dehydroaromatization. Applied Catalysis A: General 2018, 552, 11-20. 2.Xu, Y. D.; Bao, X. H.; Lin, L. W., Direct conversion of methane under nonoxidative conditions. J. Catal. 2003, 216 (1-2), 386-395. 3.Christiaan H.L.Tempelman,Xiaochun Zhu,Emiel J.M.Hensen.用于甲烷芳构化的Mo/HZSM-5催化剂的活化[J].催化学报,2015,36(06):829-837. 4.Sedelnikova, O. V.; Stepanov, A. A.; Zaikovskii, V. I.; Korobitsyna, L. L.; Vosmerikov, A. V., Preparation method effect on the physicochemical and catalytic properties of a methane dehydroaromatization catalyst. Kinetics and Catalysis 2017, 58 (1), 51-57. 5.Kee, B.; Karakaya, C.; Zhu, H.; DeCaluwe, S.; Kee, R. J., The Influence of Hydrogen-Permeable Membranes and Pressure on Methane Dehydroaromatization in Packed-Bed Catalytic Reactors. Industrial Li, G.; Yarulina, I.; Kosinov, N.; Hensen, E. J.; Houben, K.; Mance, D.; Baldus, M.; Gascon, J.; Kapteijn, F., Relevance of the Mo-precursor state in H-ZSM-5 for methane dehydroaromatization. Catalysis Science Jiao, X.; Lin, M.; Wang, K.; Jia, L.; Hou, B.; Li, D., Coke distribution determines the lifespan of hollow Mo/HZSM-5 capsule catalyst in CH4 dehydroaromatization. Catalysis Science Coumans, F. J. A. G.; Uslamin, E. A.; Wijpkema, A. S. G.; Mezari, B.; Hensen, E. J. M., Methane Dehydroaromatization by Mo/HZSM-5: Mono- or Bifunctional Catalysis？ ACS Catalysis 2017, 7 (1), 520-529. 10.Tempelman, C. H. L.; Zhu, X.; Hensen, E. J. M., Activation of Mo/HZSM-5 for methane aromatization. Chinese Journal of Catalysis 2015, 36 (6), 829-837. 11.Sakbodin, M.; Wu, Y.; Oh, S. C.; Wachsman, E. D.; Liu, D., Hydrogen-Permeable Tubular Membrane Reactor: Promoting Conversion and Product Selectivity for Non-Oxidative Activation of Methane over an Fe(c)SiO2 Catalyst. Angew Chem Int Ed Engl 2016, 55 (52), 16149-16152. 12.Zhang, Z.-G., Process, reactor and catalyst design: Towards application of direct conversion of methane to aromatics under nonoxidative conditions. Carbon Resources Conversion 2019, 2 (3), 157-174. 13.Tan, P., The catalytic performance of Mo-impregnated HZSM-5 zeolite in CH 4 aromatization: Strong influence of Mo loading and pretreatment conditions. Catalysis Communications 2018, 103, 101-104. 14.Cao, Z.; Jiang, H.; Luo, H.; Baumann, S.; Meulenberg, W. A.; Assmann, J.; Mleczko, L.; Liu, Y.; Caro, J., Natural gas to fuels and chemicals: improved methane aromatization in an oxygen-permeable membrane reactor. Angew Chem Int Ed Engl 2013, 52 (51), 13794-7. 15.Xue, J.; Chen, Y.; Wei, Y.; Feldhoff, A.; Wang, H.; Caro, J., Gas to Liquids: Natural Gas Conversion to Aromatic Fuels and Chemicals in a Hydrogen-Permeable Ceramic Hollow Fiber Membrane Reactor. ACS Catalysis 2016, 6 (4), 2448-2451. 16.Morejudo, S. H.; Zanon, R.; Escolastico, S.; Yuste-Tirados, I.; Malerod-Fjeld, H.; Vestre, P. K.; Coors, W. G.; Martinez, A.; Norby, T.; Serra, J. M.; Kjolseth, C., Direct conversion of methane to aromatics in a catalytic co-ionic membrane reactor. Science 2016, 353 (6299), 563-6. 17.Zhu, P.; Yang, G.; Sun, J.; Fan, R.; Zhang, P.; Yoneyama, Y.; Tsubaki, N., A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization. Journal of Materials Chemistry A 2017, 5 (18), 8599-8607. 18.王迪勇,王金渠,杨建华,鲁金明,殷德宏,张艳.蒸气相法ZSM-5分子筛的合成及其负载的Mo催化剂在甲烷芳构化中的应用[J].催化学报,2012,33(08):1383-1388. 19.Liu, H.; Bao, X.; Xu, Y., Methane dehydroaromatization under nonoxidative conditions over Mo/HZSM-5 catalysts: Identification and preparation of the Mo active species. J. Catal. 2006, 239 (2), 441-450. 20.Chu, N.; Yang, J.; Li, C.; Cui, J.; Zhao, Q.; Yin, X.; Lu, J.; Wang, J., An unusual hierarchical ZSM-5 microsphere with good catalytic performance in methane dehydroaromatization. Microporous and Mesoporous Materials 2009, 118 (1), 169-175.
4. 毕业设计（论文）计划
2-3月：文献检索及撰写开题报告；3-4月：Mo/HZSM-5催化剂用于甲烷芳构化固定床反应的测试；4-5月：甲烷芳构化填充床膜反应器反应条件考察；5-6月：毕业论文撰写与修正。
