丙烯/丙烷吸附分离的动态研究任务书

 2022-01-22 11:01

全文总字数:4281字

1. 毕业设计(论文)的内容和要求

1.查阅相关文献了解目前丙烯丙烷分离的研究现状,了解课题相关背景,已有成果以及存在的问题,对论文的研究方向有较深入的认识。

2.增强分析问题解决问题的能力,培养独立思考及动手做实验的能力。

3.了解实验仪器的具体使用方法和常规的表征方法。

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2. 实验内容和要求

1.系统的检索文献,撰写开题报告。

2.设计具体的动态研究流程。

3.对吸附剂进行筛选,并进行相关结构表征和静态吸附的测试。

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3. 参考文献

(1) Eldridge, R. B. Olefin/Paraffin Separation Technology: A Review. Ind. Eng. Chem. Res. 1993, 32, 22082212.(2) Da Silva, F. A.; Rodrigues, A. E. Adsorption Equilibria and Kinetics for Propylene and Propane over 13X and 4A Zeolite Pellets. Ind. Eng. Chem. Res. 1999, 38, 20512057.(3) Granato, M. A.; Vlugt, T. J. H.; Rodrigues, A. E. Molecular Simulation of PropanePropylene Binary Adsorption Equilibrium in Zeolite 4A. Ind. Eng. Chem. Res. 2007, 46, 321328(4) Grande, C. A.; Gigola, C.; Rodrigues, A. E. Propane-Propylene Binary Asorption on Zeolite 4A. Adsorption 2003, 9, 321329(5) Grande, C. A.; Cavenati, S.; Barcia, P.; Hammer, J.; Fritz, H. G.; Rodrigues, A. E. Adsorption of Propane and Propylene in Zeolite 4AHoneycomb Monolith. Chem. Eng. Sci. 2006, 61, 30533067.(6) Padin, J.; Rege, S. U.; Yang, R. T.; Cheng, L. S. Molecular Sieve Sorbents for Kinetic Separation of Propane/Propylene. Chem. Eng. Sci.2000, 55, 45254535.(7) Grande, C. A.; Gigola, C.; Rodrigues, A. E. Adsorption of Propane and Propylene in Pellets and Crystals of 5A Zeolite. Ind. Eng. Chem. Res. 2002, 41, 8592.(8) Granato, M. A.; Vlugt, T. J. H.; Rodrigues, A. E. Molecular Simulation of PropanePropylene Binary Adsorption Equilibrium in Zeolite 13X. Ind. Eng. Chem. Res. 2007, 46, 72397245(9) Grande, C. A.; Gascon, J.; Kapteijn, F.; Rodrigues, A. E. Propane/Propylene Separation with Li-Exchanged Zeolite 13X. Chem. Eng. J. 2010, 160, 207214(10) Campo, M. C.; Ribeiro, A. M.; Ferreira, A.; Santos, J. C.; Lutz, C.; Loureiro, J. M.; Rodrigues, A. E. New 13X Zeolite for Propylene/Propane Separation by Vacuum Swing Adsorption. Sep. Purif. Technol.2013, 103, 6070.(11) Narin, G.; Martins, V. F. D.; Campo, M.; Ribeiro, A. M.; Ferreira, A.; Santos, J. C.; Schumann, K.; Rodrigues, A. E. Light Olefins/Paraffins Separation with 13X Zeolite Binderless Beads. Sep. Purif. Technol. 2014, 133, 452475.(12) Zhu, W.; Kapteijn, F.; Moulijn, J. A. Shape Selectivity in the Adsorption of Propane/Propene on the All-Silica DD3R. Chem. Commun. 1999, 24, 24532454(13) Gascon, J.; Blom, W.; van Miltenburg, A.; Ferreira, A.; Berger, R.; Kapteijn, F. Accelerated Synthesis of All-Silica DD3R and Its Performance in the Separation of Propylene/Propane Mixtures. Microporous Mesoporous Mater. 2008, 115, 585593(14) Khalighi, M.; Chen, Y. F.; Farooq, S.; Karimi, I. A.; Jiang, J. W.Propylene/Propane Separation Using SiCHA. Ind. Eng. Chem. Res. 2013, 52, 38773892.(15) Gutierrez-Sevillano, J. J.; Dubbeldam, D.; Rey, F.; Valencia, S.; Palomino, M.; Martin-Calvo, A.; Calero, S. Analysis of the ITQ-12 Zeolite Performance in PropanePropylene Separations Using a Combination of Experiments and Molecular Simulations. J. Phys. Chem. C 2010, 114, 1490714914.(16) Horst, J. H.; Bromley, S. T.; van Rosmalen, G. M.; Jansen, J. C. Molecular Modelling of the Transport Behaviour of C3 and C4 Gases through the Zeolite DD3R. Microporous Mesoporous Mater. 2002, 53, 4557.(17) Maghsoudi, H. Equilibrium Adsorption Analysis of Microporous Adsorbents in Propene/Propane Binary Mixture Separation. Adsorption 2015, 21, 547556.(18) Li, K.; Olson, D. H.; Seidel, J.; Emge, T. J.; Gong, H.; Zeng, H.; Li, J. Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene. J. Am. Chem. Soc. 2009, 131, 1036810369(19) Plaza, M. G.; Ribeiro, A. M.; Ferreira, A.; Santos, J. C.; Lee, U.-H.; Chang, J.-S.; Loureiro, J. M.; Rodrigues, A. E. Propylene/Propane Separation by Vacuum Swing Adsorption Using Cu-BTC Spheres. Sep. Purif. Technol. 2012, 90, 109119.(20) Ferreira, A. F. P.; Santos, J. C.; Plaza, M. G.; Lamia, N.; Loureiro, J. M.; Rodrigues, A. E. Suitability of Cu-BTC Extrudates for Propanepropylene Separation by Adsorption Processes. Chem. Eng. J. 2011, 167, 112.

4. 毕业设计(论文)计划

2021.1.18-2021.3.10 查阅收集文献资料,了解课题背景,完成开题报告的撰写,为实验作准备工作。

2021.3.11-2021.3.31 筛选吸附剂,设计动态实验。

2021.4.1-2021.4.30 对吸附剂进行相应的表征测试,开展动态吸附研究,并且撰写中期自查表2021.5.1-2021.5.30 研究不同条件下的动态吸附性能,同时撰写毕业论文。

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