基于溶剂化胺修饰的纳滤膜表面电性梯度调控及分离设计任务书

 2022-01-22 11:01

全文总字数:4257字

1. 毕业设计(论文)的内容和要求

主要内容:(1)摘要:论文课题的基本背景和意义。

(2)文献综述:纳滤的基本介绍、影响纳滤膜性能的因素、电荷调控手段、本课题的意义。

(3)实验与结果讨论:介绍论文的主要工作以及得出的结论。

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2. 实验内容和要求

1. 学会水处理纳滤膜的基本制备方法,包括界面聚合、非溶剤相转化法制基膜、表面接枝;2. 学会使用常用的科研软件,包括origin、word、PPT绘图;3. 学会分析纳滤膜常规表征的结果(红外、XPS、亲水性表征、SEM)以及实验数据的处理;

3. 参考文献

目前的文献,后期根据需要继续添加。(1) Sarkar, P.; Modak, S.; Karan, S. Ultraselective and Highly Permeable Polyamide Nanofilms for Ionic and Molecular Nanofiltration. Adv. Funct. Mater. 2020, 2007054.(2) Xu, Y. C.; Wang, Z. X.; Cheng, X. Q.; Xiao, Y. C.; Shao, L. Positively charged nanofiltration membranes via economically mussel-substance-simulated co-deposition for textile wastewater treatment. Chem. Eng. J. 2016, 303, 555.(3) Zhu, J. Y.; Tian, M. M.; Hou, J. W.; Wang, J.; Lin, J. Y.; Zhang, Y. T.; Liu, J. D.; Van der Bruggen, B. Surface zwitterionic functionalized graphene oxide for a novel loose nanofiltration membrane. J. Mater. Chem. A 2016, 4 (5), 1980.(4) Ye, W. Y.; Liu, R. R.; Chen, X. Y.; Chen, Q.; Lin, J. Y.; Lin, X. C.; Van der Bruggen, B.; Zhao, S. F. Loose nanofiltration-based electrodialysis for highly efficient textile wastewater treatment. J. Membr. Sci 2020, 608, 118182.(5) Li, Y.; Zhu, J. Y.; Li, S.; Guo, Z.; Van der Bruggen, B. Flexible Aliphatic-Aromatic Polyamide Thin Film Composite Membrane for Highly Efficient Organic Solvent Nanofiltration. ACS Appl. Mater. Inter. 2020, 12 (28), 31962.(6) Bandini, S. Modelling the mechanism of charge formation in NF membranes: Theory and application. J. Membr. Sci 2005, 264 (1-2), 75.(7) Bowen, W. R.; Mohammad, A. W.; Hilal, N. Characterisation of nanofiltration membranes for predictive purposes - Use of salts, uncharged solutes and atomic force microscopy. J. Membr. Sci 1997, 126 (1), 91.(8) Bandini, S.; Vezzani, D. Nanofiltration modeling: the role of dielectric exclusion in membrane characterization. Chem. Eng. Sci. 2003, 58 (15), 3303.(9) Ni, L. H.; Liao, Z. P.; Chen, K.; Xie, J.; Li, Q.; Qi, J. W.; Sun, X. Y.; Wang, L. J.; Li, J. S. Defect-engineered UiO-66-NH2 modified thin film nanocomposite membrane with enhanced nanofiltration performance. Chem. Commun. 2020, 56 (60), 8372.(10) Wang, J.; Zhu, J. Y.; Tsehaye, M. T.; Li, J.; Dong, G. Y.; Yuan, S. S.; Li, X.; Zhang, Y. T.; Liu, J. D.; Van der Bruggen, B. High flux electroneutral loose nanofiltration membranes based on rapid deposition of polydopamine/polyethyleneimine. J. Mater. Chem. A 2017, 5 (28), 14847.(11) Wang, J.; Zhang, Y. T.; Zhu, J. Y.; Hou, J. W.; Liu, J. D.; Van der Bruggen, B. Zwitterionic functionalized layered double hydroxides nanosheets for a novel charged mosaic membrane with high salt permeability. J. Membr. Sci. 2016, 510, 27.(12) Ma, T. Y.; Su, Y. L.; Li, Y. F.; Zhang, R. N.; Liu, Y. N.; He, M. R.; Li, Y.; Dong, N. X.; Wu, H.; Jiang, Z. Y. Fabrication of electro-neutral nanofiltration membranes at neutral pH with antifouling surface via interfacial polymerization from a novel zwitterionic amine monomer. J. Membr. Sci. 2016, 503, 101.(13) Zhang, N.; Jiang, B.; Zhang, L. H.; Huang, Z. H.; Sun, Y. L.; Zong, Y.; Zhang, H. M. Low-pressure electroneutral loose nanofiltration membranes with polyphenol-inspired coatings for effective dye/divalent salt separation. Chem. Eng. J. 2019, 359, 1442.(14) Ba, C. Y.; Economy, J. Preparation and characterization of a neutrally charged antifouling nanofiltration membrane by coating a layer of sulfonated poly(ether ether ketone) on a positively charged nanofiltration membrane. J. Membr. Sci. 2010, 362 (1-2), 192.(15) Li, Q.; Liao, Z. P.; Fang, X. F.; Wang, D. P.; Xie, J.; Sun, X. Y.; Wang, L. J.; Li, J. S. Tannic acid-polyethyleneimine crosslinked loose nanofiltration membrane for dye/salt mixture separation. J. Membr. Sci. 2019, 584, 324.(16) Soyekwo, F.; Zhang, Q. G.; Gao, R. S.; Qu, Y.; Lv, R. X.; Chen, M. M.; Zhu, A. M.; Liu, Q. L. Metal in situ surface functionalization of polymer-grafted-carbon nanotube composite membranes for fast efficient nanofiltration. J. Mater. Chem. A 2017, 5 (2), 583.

4. 毕业设计(论文)计划

2021年3月10日前:完成外文翻译、文献综述、课题研究方案等工作。

2021年4月10日前:进行课题的具体设计和实验操作。

2021年5月10日前:完成实验结果的处理与分析、完成毕业论文的框架和大致内容。

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