无机-有机杂化材料MIL-100Fe的快速合成和气体传感性质研究任务书

 2022-02-10 07:02

全文总字数:4181字

1. 毕业设计(论文)的内容和要求

在无机-有机杂化材料中,其中有机与无机组份的微区尺寸均达到纳米级,有的甚至达到分子水平级,最 终达到兼备有机和无机材料的特点,在光学透明性、可调折射率、力学性能、耐磨损、耐高温、柔韧性 等性能等方面,无机-有机材料均表现出单纯有机高分子材料或无机材料所不具备的优越性能。

近年来,柔性器件在传感领域得到广泛应用。

传感器的柔性化已成为提高其应用优势的重要手段。

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2. 实验内容和要求

1. 掌握金属配合物的基本合成方法和实验室安全知识。

2. 熟练操作红外,紫外-可见光谱仪及谱图分析。

3. 熟悉使用粉末衍射仪、热重分析仪。

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3. 参考文献

(1) Duan, C.; Yu, Y.; Yang, P.; Zhang, X.; Li, F.; Li, L.; Xi, H. Engineering New Defects in MIL-100(Fe) via a Mixed-Ligand Approach To Effect Enhanced Volatile Organic Compound Adsorption Capacity. Ind. Eng. Chem. Res. 2020, 59 (2), 774782. (2) Luo, Y.; Tan, B.; Liang, X.; Wang, S.; Gao, X.; Zhang, Z.; Fang, Y. Low-Temperature Rapid Synthesis and Performance of the MIL-100(Fe) Monolithic Adsorbent for Dehumidification. Ind. Eng. Chem. Res. 2020, 59 (16), 72917298. (3) Souza, B. E.; M?slein, A. F.; Titov, K.; Taylor, J. D.; Rudi?, S.; Tan, J.-C. Green Reconstruction of MIL-100 (Fe) in Water for High Crystallinity and Enhanced Guest Encapsulation. ACS Sustain. Chem. Eng. 2020, 8 (22), 82478255. (4) Seo, Y.-K.; Chitale, S. K.; Lee, U.-H.; Patil, P.; Chang, J.-S.; Hwang, Y. K. Formation of Polyaniline-MOF Nanocomposites Using Nano-Sized Fe(III)-MOF for Humidity Sensing Application. J. Nanosci. Nanotechnol. 2019, 19 (12), 81578162. (5) Zhu, T.; Sun, Y.; Wang, Y.; Xing, H.; Li, X.; Hu, P.; Zong, Y.; Zheng, X. A MOF-Driven Porous Iron with High Dielectric Loss and Excellent Microwave Absorption Properties. J. Mater. Sci. Mater. Electron. 2020, 31 (9), 68436854.(6) Cui, L.; Zhao, D.; Yang, Y.; Wang, Y.; Zhang, X. Synthesis of Highly Efficient α-Fe 2 O 3 Catalysts for CO Oxidation Derived from MIL-100(Fe). J. Solid State Chem. 2017, 247, 168172.(7)Hindocha, S.; Poulston, S. Study of the Scale-up, Formulation, Ageing and Ammonia Adsorption Capacity of MIL-100(Fe), Cu-BTC and CPO-27(Ni) for Use in Respiratory Protection Filters. Faraday Discuss. 2017, 201, 113125. (8) Aguiar, L. W.; Otto, G. P.; Kupfer, V. L.; Fvaro, S. L.; Silva, C. T. P.; Moiss, M. P.; de Almeida, L.; Guilherme, M. R.; Radovanovic, E.; Girotto, E. M.; Rinaldi, A. W. Simple, Fast, and Low-Cost Synthesis of MIL-100 and MIL-88B in a Modified Domestic Microwave Oven. Mater. Lett. 2020, 276, 128127.(9) Li, S.; Cui, J.; Wu, X.; Zhang, X.; Hu, Q.; Hou, X. Rapid in Situ Microwave Synthesis of Fe3O4@MIL-100(Fe) for Aqueous Diclofenac Sodium Removal through Integrated Adsorption and Photodegradation. J. Hazard. Mater. 2019, 373, 408416. (10) Fang, Y.; Yang, Z.; Li, H.; Liu, X. MIL-100(Fe) and Its Derivatives: From Synthesis to Application for Wastewater Decontamination. Environ. Sci. Pollut. Res. 2020, 27 (5), 47034724. (11) Madhan Vinu; Wei-Cheng Lin; Duraisamy Senthil Raja; Jeng-Liang Han; Chia-Her Lin. Microwave-Assisted Synthesis of Nanoporous Aluminum-Based Coordination Polymers as Catalysts for Selective Sulfoxidation Reaction. Polymers 2017, 9 (12), 498. (12) Tannert, N.; G?kpinar, S.; Hastrk, E.; Nie?ing, S.; Janiak, C. Microwave-Assisted Dry-Gel Conversion-a New Sustainable Route for the Rapid Synthesis of MetalOrganic Frameworks with Solvent Re-Use. Dalton Trans. 2018, 47 (29), 98509860. (13) Xiao, J.-D.; Qiu, L.-G.; Jiang, X.; Zhu, Y.-J.; Ye, S.; Jiang, X. Magnetic Porous Carbons with High Adsorption Capacity Synthesized by a Microwave-Enhanced High Temperature Ionothermal Method from a Fe-Based Metal-Organic Framework. Carbon 2013, 59, 372382.(14) Huang, J.; Song, H.; Chen, C.; Yang, Y.; Xu, N.; Ji, X.; Li, C.; You, J.-A. Facile Synthesis of N-Doped TiO2 Nanoparticles Caged in MIL-100(Fe) for Photocatalytic Degradation of Organic Dyes under Visible Light Irradiation. J. Environ. Chem. Eng. 2017, 5 (3), 25792585. (15) Xu, J.; Xu, J.; Jiang, S.; Cao, Y.; Xu, K.; Zhang, Q.; Wang, L. Facile Synthesis of a Novel Ag3PO4/MIL-100(Fe) Z-Scheme Photocatalyst for Enhancing Tetracycline Degradation under Visible Light. Environ. Sci. Pollut. Res. 2020.

4. 毕业设计(论文)计划

1.2020.12 任务书下达,学生查阅文献,做好开题前期工作。

2.2020.12-2021.3:在广泛查阅资料的基础上,完善课题研究方案,完成外文翻译、文献综述和开题报告等工作。

3.2021.3-2021.5:进行课题的实验及结果的处理与分析等,完成毕业论文写作和修改完善。

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